Advertisements
Advertisements
Question
Give the oxidation state, d-orbital occupation and coordination number of the central metal ion in the following complex:
(NH4)2[CoF4]
Solution
Oxidation state = +2,
Coordination number = 4,
d7 configuration = \[\ce{t^5_{2g}e^2_g}\]
APPEARS IN
RELATED QUESTIONS
What is the coordination entity formed when excess of aqueous KCN is added to an aqueous solution of copper sulphate? Why is it that no precipitate of copper sulphide is obtained when H2S(g) is passed through this solution?
Give the oxidation state, d-orbital occupation and coordination number of the central metal ion in the following complex:
cis-[CrCl2(en)2]Cl
Write IUPAC names of the following compounds
Write IUPAC names of the following compounds:
Which of the following represents a chelate ligand?
The coordination number of the central ion may be obtained from:
Which of the following complexes formed by \[\ce{Cu^2+}\] ions is most stable?
When 1 mol \[\ce{CrCl3.6H2O}\] is treated with excess of \[\ce{AgNO3}\], 3 mol of \[\ce{AgCl}\] are obtained. The formula of the complex is ______.
Which of the following complexes are heteroleptic?
(i) \[\ce{[Cr(NH3)6]^{3+}}\]
(ii) \[\ce{[Fe(NH3)4]Cl2]^+}\]
(iii) \[\ce{[Mn(CN)6]^{4-}}\]
(iv) \[\ce{[Co(NH3)4]Cl2]}\]
Arrange the following complexes in the increasing order of conductivity of their solution:
[Co(NH3)3Cl3], [Co(NH3)4Cl2]Cl, [Co(NH3)6]Cl3, [Cr(NH3)5Cl]Cl2
A coordination compound \[\ce{CrCl3.4H2O}\] precipitates silver chloride when treated with silver nitrate. The molar conductance of its solution corresponds to a total of two ions. Write structural formula of the compound and name it.
Match the coordination compounds given in Column I with the central metal atoms given in Column II and assign the correct code:
Column I (Coordination Compound) | Column II (Central metal atom) |
A. Chlorophyll | 1. rhodium |
B. Blood pigment | 2. cobalt |
C. Wilkinson catalyst | 3. calcium |
D. Vitamin B12 | 4. iron |
5. magnesium |
Assertion: \[\ce{Cr(H2O)6]Cl2 and [Fe(H2O)6]Cl2}\] are reducing in nature.
Reason: Unpaired electrons are present in their d-orbitals.
Which one of the following ligands forms a chelate?
The co-ordinate number and the oxidation state of the element E in the complex [E(en)2(C2O4)]NO2 are respectively?
The oxidation number d-arbitral occupation and co-ordination number of Cr in the complex cis [Cr(en)2Cl2]Cl are respectively.
Metal attached with EDTA in an octahedral complex, has coordination number ______.
Ethylene diaminetetraacetate (EDTA) ion is ______
Explain the following, giving two examples:
Coordination number
Give two examples of didentate ligand.