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Aluminium crystallises in a cubic close-packed structure. Its metallic radius is 125 pm. (i) What is the length of the side of the unit cell? (ii) How many unit cells are there in 1.00 cm3 of aluminium? - Chemistry

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प्रश्न

Aluminium crystallises in a cubic close-packed structure. Its metallic radius is 125 pm.

(i) What is the length of the side of the unit cell?

(ii) How many unit cells are there in 1.00 cm3 of aluminium?

उत्तर

(i) For cubic close-packed structure:

`a = 2sqrt2r`

`= 2sqrt2xx125 pm`

= 353.55 pm

= 354 pm (approximately)

(ii) 

Volume of one unit cell = (354 pm)3

= 4.4 × 107 pm3

= 4.4 × 107 × 10−30 cm3

= 4.4 × 10−23 cm3

Therefore, number of unit cells in 1.00 cm3 = `(1.00 cm^3)/(4.4xx10^(-23) cm^(3)`

= 2.27 x1022

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Close Packed Structures of Solids
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अध्याय 1: The Solid State - Exercises [पृष्ठ ३२]

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एनसीईआरटी Chemistry [English] Class 12
अध्याय 1 The Solid State
Exercises | Q 24 | पृष्ठ ३२

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