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Give a reason for the following: Mn+2 compounds are more stable than Fe+2 compounds. - Chemistry (Theory)

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प्रश्न

Give a reason for the following:

Mn+2 compounds are more stable than Fe+2 compounds.

संक्षेप में उत्तर

उत्तर

Mn2+ = 1s2 2s2 2p6 3s2 3p6 3d5 (Half-filles d-orbital)

Fe2+ = 1s2 2s2 2p6 3s2 3p6 3d

Mn2+ molecules are more stable because of their half-filled d-orbitals. Fe2+ complexes are less stable because they have six electrons in the 3d-orbital. Hence, they loose one electron to get stable 3d5 configuration.

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