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प्रश्न
Give reason to explain why ClF3 exists but FCl3 does not exist.
उत्तर
Chlorine has vacant d-orbitals, which become excited upon bonding when electrons from the 3p-orbital are promoted to the 3d-orbital, giving it a covalency of three.
Due to the lack of unoccupied d-orbitals in the second energy shell, fluorine cannot expand its octet. As a result, it can only have one covalency.
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संबंधित प्रश्न
Compare the oxidizing action of F2 and Cl2 by considering parameters such as bond dissociation enthalpy, electron gain enthalpy and hydration enthalpy.
F2 has lower bond dissociation enthalpy than Cl2. Why?
With what neutral molecule is ClO− isoelectronic? Is that molecule a Lewis base?
Cl2 acts as a bleaching agent.
Tincture of iodine is ____________.
The set with the correct order of acidity is:
Reduction potentials of some ions are given below. Arrange them in decreasing order of oxidising power.
| Ion | \[\ce{CIO^{-}_{4}}\] | \[\ce{IO^{-}_{4}}\] | \[\ce{BrO^{-}_{4}}\] |
| Reduction potential EΘ/V |
EΘ = 1.19 V | EΘ = 1.65V | EΘ = 1.74 V |
Which of the following is isoelectronic pair?
Iodine has lowest oxidiation state in ______.
Statement I: Acid strength increases in the order given as HF << HCl << HBr << HI.
Statement II: As the size of the elements F, Cl, Br, and I increase down the group, the bond strength of HF, HCl, HBr and HI decreases and so the acid strength increases.
In light of the above statements, choose the correct answer from the options given below.
