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प्रश्न
Give one test to differentiate \[\ce{[Co(NH3)5Cl]SO4}\] and \[\ce{[Co(NH3)5SO4]Cl}\].
उत्तर
\[\ce{[Co(NH3)5Cl]SO4 -> [Co(NH3)5Cl]^{+2} + SO^2-_4}\]
\[\ce{[Co(NH3)5SO4]Cl -> [Co(NH3)5Cl]SO4}\]
1. Aqueous solution of (a) gives sulphate ion. When the addition of BaCl, solution (a) gives a white precipitate of BaSO4. But (b) does not give any precipitate.
2. Aqueous solution of (b) gives chloride ion. When the addition of AgNO3 solution (b) gives curdy white precipitate of AgCl. But (a) does not give any precipitate.
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संबंधित प्रश्न
The sum of primary valence and secondary valence of the metal M in the complex [M(en)2(Ox)]Cl is ____________.
Crystal field stabilization energy for high spin d5 octahedral complex is ____________.
Arrange the following in order of increasing molar conductivity.
i) \[\ce{Mg[Cr(NH3) (Cl)5]}\]
ii) \[\ce{[Cr(NH3)5 Cl]3 [CoF6]2}\]
iii) \[\ce{[Cr(NH3)3 Cl3]}\]
Give an example for a complex of the type [Ma2b2c2] where a, b, c are monodentate ligands and give the possible isomers.
In an octahedral crystal field, draw the figure to show the splitting of d orbitals.
Why tetrahedral complexes do not exhibit geometrical isomerism.
What is crystal field stabilization energy (CFSE)?
A solution of \[\ce{[Ni(H2O)6]^2+}\] is green, whereas a solution of \[\ce{[Ni(CN)4]^2-}\] is colorless – Explain.
Discuss briefly the nature of bonding in metal carbonyls.
Write the oxidation state, coordination number, nature of ligand, magnetic property and electronic configuration in octahedral crystal field for the complex \[\ce{K4[Mn(CN)6]}\].
