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प्रश्न
Give one test to differentiate \[\ce{[Co(NH3)5Cl]SO4}\] and \[\ce{[Co(NH3)5SO4]Cl}\].
उत्तर
\[\ce{[Co(NH3)5Cl]SO4 -> [Co(NH3)5Cl]^{+2} + SO^2-_4}\]
\[\ce{[Co(NH3)5SO4]Cl -> [Co(NH3)5Cl]SO4}\]
1. Aqueous solution of (a) gives sulphate ion. When the addition of BaCl, solution (a) gives a white precipitate of BaSO4. But (b) does not give any precipitate.
2. Aqueous solution of (b) gives chloride ion. When the addition of AgNO3 solution (b) gives curdy white precipitate of AgCl. But (a) does not give any precipitate.
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संबंधित प्रश्न
The sum of primary valence and secondary valence of the metal M in the complex [M(en)2(Ox)]Cl is ____________.
Crystal field stabilization energy for high spin d5 octahedral complex is ____________.
Choose the correct statement.
Arrange the following in order of increasing molar conductivity.
i) \[\ce{Mg[Cr(NH3) (Cl)5]}\]
ii) \[\ce{[Cr(NH3)5 Cl]3 [CoF6]2}\]
iii) \[\ce{[Cr(NH3)3 Cl3]}\]
In an octahedral crystal field, draw the figure to show the splitting of d orbitals.
Why tetrahedral complexes do not exhibit geometrical isomerism.
What is crystal field splitting energy?
A solution of \[\ce{[Ni(H2O)6]^2+}\] is green, whereas a solution of \[\ce{[Ni(CN)4]^2-}\] is colorless – Explain.
What are the limitations of VB theory?
Write the oxidation state, coordination number, nature of ligand, magnetic property and electronic configuration in octahedral crystal field for the complex \[\ce{K4[Mn(CN)6]}\].
