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Show that the Circumference of the Bohr Orbit for the Hydrogen Atom is an Integral Multiple of the De Broglie Wavelength Associated with the Electron Revolving Around the Orbit - Chemistry

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प्रश्न

Show that the circumference of the Bohr orbit for the hydrogen atom is an integral multiple of the de Broglie wavelength associated with the electron revolving around the orbit.

संख्यात्मक

उत्तर

Since a hydrogen atom has only one electron, according to Bohr’s postulate, the angular momentum of that electron is given by:

`"mvr" = "n" "h"/(2pi) `   ....(1)

Where,

n = 1, 2, 3, …

According to de Broglie’s equation:

`lambda = "h"/("mv")`

or `"mv" = ("h"/lambda)`  ....(2)

Substituting the value of ‘mv’ from expression (2) in expression (1):

`("hr")/lambda = "n" "h"/(2pi)`

or `2pi"r" = "n"lambda`  .....(3)

Since ‘2π"r"’ represents the circumference of the Bohr orbit (r), it is proved by equation (3) that the circumference of the Bohr orbit of the hydrogen atom is an integral multiple of de Broglie’s wavelength associated with the electron revolving around the orbit.

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अध्याय 2: Structure of Atom - EXERCISES [पृष्ठ ७१]

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एनसीईआरटी Chemistry - Part 1 and 2 [English] Class 11
अध्याय 2 Structure of Atom
EXERCISES | Q 2.32 | पृष्ठ ७१

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How are various lines of Lyman series formed? Explain on the basis of Bohr’s theory.


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  1. State the type of spectrum obtained.
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