Advertisements
Advertisements
प्रश्न
What is the action of nitrous acid on secondary nitroalkane?
उत्तर
Secondary nitroalkanes react with nitrous acid to form corresponding blue coloured nitroso-nitroalkanes, which are insoluble in sodium hydroxide as they no more contain replaceable α-hydrogen atom.
APPEARS IN
संबंधित प्रश्न
How are 1 - nitropropane, 2-nitropropane and 2-methyl 2- nitropropane are distinguished from each other using nitrous acid?
Primary and secondary nitroalcanes containing α - H atom show property of -
- chain isomerism
- tautomerism
- optical isomerism
- geometrical isomerism
Distinguish between the following pairs of compounds: Aniline and N-methylaniline
Describe a method for the identification of primary, secondary and tertiary amines. Also write chemical equations of the reactions involved.
When primary amine reacts with CHCl3 in alcoholic KOH, the product is _______.
(A) aldehyde
(B) alcohol
(C) cyanide
(D) an isocyanide
What is the action of Benzene Sulphonyl Chloride on primary, secondary and tertiary
amines?
What is the action of nitrous acid on tertiary nitroalkane
Describe Hinsberg method for the identification of primary, secondary and tertiary amines. Also write the chemical equations of the reactions involved.
Which of the following reactions will not give a primary amine?
Primary, secondary and tertiary amines may be separated by using ______.
Identify the compound that will react with Hinsberg’s reagent to give a solid which dissolves in alkali.
Arrange the following in the increasing order of their boiling points:
A: Butanamine
B: N, N-Dimethylethanamine
C: N- Etthylethanaminamine
Compound A is converted to B on reaction with CHCl3 and KOH. The compound B is toxic and can be decomposed by C. A, B and C respectively are ______.
Isocyanide reaction involves the intermediate formation of ______.
Which of the following is not a correct statement for primary aliphatic amines?
Match List I with List II.
| List I | List II | ||
| (A) | Benzenesulphonyl chloride | (I) | Test for primary amines |
| (B) | Hoffmann bromamide reaction | (II) | Anti Saytzeff |
| (C) | Carbylamine reaction | (III) | Hinsberg reagent |
| (D) | Hoffmann orientation | (IV) | Known reaction of Isocyanates |
Choose the correct answer from the options given below:
A compound 'X' on treatment with Br2/NaOH, provided C3H9N, which gives positive carbylamine test. Compound 'X' is ______.
Give reasons:
(CH3)2NH is more basic than (CH3)3N in an aqueous solution.
Explain why (CH3)2NH is more basic than (CH3)3N in aqueous solution.
In the reaction \[\ce{C6H5NH2 + CHCl3 + 3KOH -> A + 3B + 3C}\] the product A is:
Carbylamine test is the distinguishing test for ______.
Among dimethylamine (pKb = 3.27) and diethylamine (pKb = 3.0), which one is more basic?
