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प्रश्न
What is called homologous series? Give any three of its characteristics?
उत्तर
A homologous series is a group or a class of organic compounds having the same general formula and similar chemical properties in which the successive members differ by a -CH2 group.
Characteristics of homologous series:
- Each member of the series differs from the proceeding or succeeding member by one methylene group (-CH2) and hence by a molecular mass of 14 amu.
- All members of a homologous series contain the same elements and functional group.
- They are represented by a general molecular formula. Eg: Alkanes, C2H2n+2.
- The members in each homologous series show a regular gradation in their physical properties with respect to their increase in molecular mass.
- The chemical properties of the members of a homologous series are similar.
- All the members can be prepared by a common method.
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संबंधित प्रश्न
Write the name and formula of the 2nd member of homologous series having general formula CnH2n.
Give the molecular formula of one homologue of the following:
C3H6
The molecular formula of the third member of the homologous series of ketones is:
(a) C4H8O
(b) C3H6O
(c) C5H10O
(d) C6H12O
An organic compound having the molecular formula C3H6O can exist in the form of two isomers A and B having different functional groups. The isomer A is a liquid which is used as a solvent for nail polish. The isomer B is also a liquid. An aqueous solution of one of the lower homologues of B is used for preserving biological specimens in the laboratory
(a) What is compound A?
(b) Write the electron-dot structure of A.
(c) What is compound B?
(d) Write the electron-dot structure of B.
(e) Name the lower homologue of compound B which is used in preserving biological specimens.
What is the difference in the molecular formula of any two adjacent homologues in terms of molecular mass?
Define homologous series of organic compounds. List its two characteristics. Write the name and formula of the first member of the series of alkenes.
Two statements are given - one labeled Assertion (A) and the other labeled Reason (R).
Assertion (A): In a homologous series of alcohols, the formula for the second member is C2H5OH and the third member is C3H7OH.
Reason (R): The difference between the molecular masses of the two consecutive members of a homologous series is 144.
Find the odd one out and give its explanation.
As one ascends in any homologous series, physical properties change gradually.
Complete the following table for homologous series of alcohols.
| Name | Molecular formula | Condensed structural formula | Number of carbon atom | Number of -CH2- units | Boiling point °C |
| Methanol | CH4O | CH3-OH | 1 | 1 | 63 |
| Ethanol | C2H6O | CH3–CH2-OH | 2 | 2 | 78 |
| Propanol | C3H8O | CH3–CH2–CH2-OH | ______ | ______ | 97 |
| Butanol | C4H10O | CH3–CH2–CH2–CH2–OH | ______ | ______ | 118 |
