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प्रश्न
What is the relationship between the members of following pairs of structures? Are they structural or geometrical isomers or resonance contributors?
\[\begin{array}{cc}\ce{^+OH}\\||\\
\ce{H - C - OH}\end{array}\]
\[\begin{array}{cc}\ce{OH}\phantom{.}\\|\phantom{...}\\
\ce{H - C^+ - OH}\end{array}\]
उत्तर
The given structures are canonical structures or contributing structures. They are hypothetical and individually do not represent any real molecule. Hence, the given pair represents resonance structures, called resonance isomers.
\[\begin{array}{cc}\ce{^+OH}\\||\\
\ce{H - C - OH}\end{array}\]
\[\begin{array}{cc}\ce{OH}\phantom{.}\\|\phantom{...}\\
\ce{H - C^+ - OH}\end{array}\]
APPEARS IN
संबंधित प्रश्न
Write IUPAC name of the product obtained by the ozonolysis of the following compound:
3,4-Dimethyl-hept-3-ene
Write IUPAC name of the product obtained by the ozonolysis of the following compound:
2-Ethylbut-1-ene
Draw the cis and trans structures of hex-2-ene. Which isomer will have higher b.p. and why?
Find out the type of isomerism exhibited by the following pair.
CH3 – CH2 – NH – CH2 - CH3 and CH3 - NH - CH2 - CH2 - CH3
Find out the type of isomerism exhibited by the following pair.
\[\begin{array}{cc}
\ce{CH3 - CH - CH2 - CH3 and CH3 - CH2 - O - CH2 - CH3}\\|\phantom{...........................................}\\
\ce{OH}\phantom{.........................................}\end{array}\]
Find out the type of isomerism exhibited by the following pair.
Find out the type of isomerism exhibited by the following pair.
Choose the correct option.
Which type of isomerism is possible in CH3 CHCHCH3?
What type(s) of isomerism is(are) shown by [Co(NH3)4Br2]Cl?
Which of the following is a functional isomer of pentan-2-ol?
The type of isomerism possible in 2-butene is ____________.
What is the relationship between the members of following pairs of structures? Are they structural or geometrical isomers or resonance contributors?
Consider structures I to VII and answer the question:
| I. | CH3 – CH2 – CH2 – CH2 – OH |
| II. | \[\begin{array}{cc} \ce{CH3 - CH2 - CH - CH3}\\ \phantom{.....}|\\ \phantom{.......}\ce{OH} \end{array}\] |
| III. | \[\begin{array}{cc} \phantom{...}\ce{CH3}\\ \phantom{}|\\ \ce{CH3 - C - CH3}\\ \phantom{}|\\ \phantom{..}\ce{OH} \end{array}\] |
| IV. | \[\begin{array}{cc} \ce{CH3 - CH - CH2 - OH}\\ |\phantom{........}\\ \ce{CH3}\phantom{......} \end{array}\] |
| V. | CH3 – CH2 – O – CH2 – CH3 |
| VI. | CH3 – O – CH2 – CH2 – CH3 |
| VII. | \[\begin{array}{cc} \ce{CH3 - O - CH - CH3}\\ \phantom{...}|\\ \phantom{......}\ce{CH3} \end{array}\] |
Identify the pairs of compounds which are functional group isomers.
Consider structures I to VII and answer the question:
| I. | CH3 – CH2 – CH2 – CH2 – OH |
| II. | \[\begin{array}{cc} \ce{CH3 - CH2 - CH - CH3}\\ \phantom{.....}|\\ \phantom{.......}\ce{OH} \end{array}\] |
| III. | \[\begin{array}{cc} \phantom{...}\ce{CH3}\\ \phantom{}|\\ \ce{CH3 - C - CH3}\\ \phantom{}|\\ \phantom{..}\ce{OH} \end{array}\] |
| IV. | \[\begin{array}{cc} \ce{CH3 - CH - CH2 - OH}\\ |\phantom{........}\\ \ce{CH3}\phantom{......} \end{array}\] |
| V. | CH3 – CH2 – O – CH2 – CH3 |
| VI. | CH3 – O – CH2 – CH2 – CH3 |
| VII. | \[\begin{array}{cc} \ce{CH3 - O - CH - CH3}\\ \phantom{...}|\\ \phantom{......}\ce{CH3} \end{array}\] |
Identify the pairs of compounds that represents position isomerism.
Compounds with same molecular formula but differing in their structures are said to be structural isomers. What type of structural isomerism is shown by
CH3 – S – CH2 – CH2 – CH3
And
\[\begin{array}{cc}
\phantom{.....................}\ce{CH3}\\
\phantom{................}/\\
\phantom{}\ce{CH3 - S - CH}\\
\phantom{...............}\backslash\\
\phantom{....................}\ce{CH3}
\end{array}\]
The molecules having dipole moment are:
(i) 2,2-Dimethylpropane
(ii) trans-Pent-2-ene
(iii) cis-Hex-3-ene
(iv) 2, 2, 3, 3 - Tetramethylbutane.
Assertion (A): The compound cyclooctane has the following structural formula: 
It is cyclic and has conjugated 8π-electron system but it is not an aromatic compound.
Reason (R): (4n + 2)π electrons rule does not hold good and ring is not planar.
Tautomerism is exhibited by ______.
Which of the following does NOT exhibit geometrical isomerism?
Ether and alcohol are ______.
The compound which shows metamerism is ______
Which type of isomerism can not be shown by benzaldoxime?
Acetamide is isomer of ______.
Which one of the following pairs are called position isomers?
The number of acyclic structural isomers (including geometrical isomers) for pentene are ______.
Which of the following pairs of compounds are positional isomers?
The number of geometrical isomers from [Co(NH3)3(NO2)3] is ______.
Which of the following pairs of compounds is an example of position isomerism?
