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Why is BiH3 The Strongest Reducing Agent Amongst All the Hydrides of Group 15 Elements? - Chemistry

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प्रश्न

Why is BiH3 the strongest reducing agent amongst all the hydrides of Group 15 elements?

उत्तर १

As we move down a group, the atomic size increases and the stability of the hydrides of group 15 elements decreases. Since the stability of hydrides decreases on moving from NH3 to BiH3, the reducing character of the hydrides increases on moving from NH3 to BiH3.

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उत्तर २

This is because as we move down the group, the size increases, as a result, length of E-H bond increases and its strength decreases, so that the bond can be broken easily to release H2 gas. Hence, BiH3 is the strongest reducing agent.

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अध्याय 7: The p-block Elements - Intext Questions [पृष्ठ १६९]

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एनसीईआरटी Chemistry [English] Class 12
अध्याय 7 The p-block Elements
Intext Questions | Q 2 | पृष्ठ १६९

संबंधित प्रश्न

The element that does NOT exhibit allotropy is

  1. As
  2. Sb
  3. Bi
  4. N

Account for the following:

N2 is less reactive at room temperature.


Arrange the following in the increasing order of property mentioned :

H3PO3, H3PO4, H3PO2 (Reducing character)

 


Discuss the trends in chemical reactivity of group 15 elements.


The group 15 element having inner electronic configuration as of argon is-

(a) Phosphorous (z = 15)

(b) Antimony (z =51)

(c) Arsenic (z = 33)

(d) Nitrogen (z = 7)

 


Account for the following :

Reducing character decreases from SO2 to TeO2


Account for the following

Bi(V) is a stronger oxidizing agent than Sb(V).


Account for the following :

N − N single bond is weaker than P − P single bond.


Account for the following :

Sulphur in vapour form exhibits paramagnetic behaviour.


What is the action of sodium on arsenic.


What is the action of Magnesium on bismuth.


Explain the geometry of [Cu(NH3)4]2+ on the basis of hybridisation [ At. No. Cu = 29 ]. 


Give reasons for the following:
E⁰ value for (Mn3+|Mn2+) is highly positive than that for (Cr3+|Cr2+) couple.


The correct order of solubility in water for He, Ne, Ar, Kr, Xe is:


Which one of the following elements is most metallic?


The correct decreasing order of basic strength is:


Which of the following is the strongest reducing agent?


If chlorine gas is passed through hot NaOH solution, two changes are observed in the oxidation number of chlorine during the reaction. These are :

(i) 0 to +5

(ii) 0 to +3

(iii) 0 to –1

(iv) 0 to +1


Basicity of ortho phosphoric acid is:-


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