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प्रश्न
Write chemical equation for the following:
Gatterman - Koch formylation
Write the chemical reactions involved in:
Gatterman Koch formylation
उत्तर
Benzene or substituted benzene is treated under high pressure with carbon-monoxide and hydrogen chloride in the presence of anhydrous aluminium chloride or cuprous chloride to give benzaldehyde or substituted benzaldehyde.
संबंधित प्रश्न
Write the structure of the product of the following reaction:
\[\ce{H3C - C ≡ C - H ->[Hg^{2+}, H2SO4]}\]
Complete the synthesis by giving missing starting material, reagent or product.
Complete the synthesis by giving missing starting material, reagent or product.
What is the action of phenyl hydrazine on propanone?
What is the action of Zn – Hg / conc. HCl on propanone?
What is the action of Sodium bisulphite on propanone?
Write only reactions for the preparation of benzophenone from benzonitrile.
Write chemical equation for the following :
Rosenmund reduction
How will you convert calcium acetate to acetaldehyde?
Answer the following in one sentence.
Name the product obtained by reacting toluene with carbon monoxide and hydrogen chloride in presence of anhydrous aluminium chloride.
What is the action of following reagents on ethanoic acid?
SOCl2/heat
What is the action of following reagents on ethanoic acid?
sodalime/heat
What is the action of following reagents on ethanoic acid?
P2O5/heat
Write reactions for the following conversions.
Benzene to Benzaldehyde
In the formation of an aldol, α-carbon atom of one aldehyde molecule attaches to ____________ of another aldehyde molecule.
Catalyst used in Rosenmund reduction is ____________.
Which of the following alcohols needs acidic KMnO4 to convert it into aldehyde or ketone?
Which of the following is called as mandelonitrile?
Rosenmund reduction of ____________ yields benzaldehyde.
Identify the compound obtained by side chain chlorination of toluene and hydrolysed further.
The reaction in which methyl group on benzene ring is converted to aldehydic group is called ______.
The product of the reaction between dimethylcadmium and acetyl chloride is ____________.
Identify the compound A and Bin following reaction.
\[\ce{CH3Cl ->[KCN(alc)][\Delta] A ->[2H2O][HCl] B + NH4Cl}\]
Identify 'A' in the following reaction:
\[\begin{array}{cc}
\phantom{...........}\ce{O}\\
\phantom{...........}||\\
\ce{2A + (C6H5CH2)2 Cd -> 2CH3 - C - CH2 - C6H5 + CdCl2}\end{array}\]
Which among the following compounds is obtained when benzene is treated with CO and HCl in presence of catalyst anhydrous AlCl3 and Cu2Cl2 under high pressure?
Which of the following compounds does NOT undergo Friedel-Crafts reaction?
What is the final product obtained when benzonitrile react with phenyl magnesium bromide in equimolar proportion?
Identify 'A' in the following reaction.
\[\ce{A ->[H2][Pd-BaSO4] C6H5CHO + HCl}\]
Which of the following is obtained by hydrogenation of benzoyl chloride in presence of Pd on BaSO4?
Identify product A in the following reaction:
\[\ce{Acetyl chloride + Dibenzylcadmium -> A}\]
Chromyl chloride converts methyl group to a chromium complex, which on acid hydrolysis gives corresponding aldehyde. This reaction is called ____________.
How ketones are prepared from nitriles?
Give the reactions involved in the Etard's reaction.
Ozonolysis of 2, 3 dimethyl but-2-ene, followed by decomposition by Zn dust and water gives ______.
How butanone is prepared from alcohol?
How are the following compound obtained by hydration of alkenes?
Ethyl alcohol
How are the following compound obtained by hydration of alkenes?
Isopropyl alcohol
How are the following compound obtained by hydration of alkenes?
tert-butyl alcohol
Write the name of the product formed when ethanoyl chloride is treated with dimethyl cadmium.
Write preparation of propanone by using ethanoyl chloride and dimethyl cadmium.
