Advertisements
Advertisements
Questions
Write chemical equation for the following:
Gatterman - Koch formylation
Write the chemical reactions involved in:
Gatterman Koch formylation
Solution
Benzene or substituted benzene is treated under high pressure with carbon-monoxide and hydrogen chloride in the presence of anhydrous aluminium chloride or cuprous chloride to give benzaldehyde or substituted benzaldehyde.
RELATED QUESTIONS
Write the structure of the product of the following reaction:
\[\ce{H3C - C ≡ C - H ->[Hg^{2+}, H2SO4]}\]
Complete the synthesis by giving missing starting material, reagent or product.
Complete the synthesis by giving missing starting material, reagent or product.
What is the action of phenyl hydrazine on propanone?
What is the action of Zn – Hg / conc. HCl on propanone?
What is the action of Sodium bisulphite on propanone?
Write the IUPAC name of the follow
\[\begin{array}\ce{\phantom{--..}O}\\\ce{\phantom{--..}||}\\ \ce{CH2=CH-C-CH3}\end{array}\]
Complete the following reaction:
\[\ce{(C6H5CH2)2Cd + 2CH3COCI}\]
Answer the following in one sentence.
Write reaction showing conversion of ethanenitrile into ethanol.
Answer the following in one sentence.
Predict the product of the following reaction:
\[\ce{CH3 - CH2 - COOCH3->[i) AIH(i-Bu)_2][ii) H3O+]}\]?
Answer the following in one sentence.
Name the product obtained by reacting toluene with carbon monoxide and hydrogen chloride in presence of anhydrous aluminium chloride.
What is the action of following reagents on ethanoic acid?
SOCl2/heat
Write reactions for the following conversions.
Benzene to Benzaldehyde
The formation of aldehyde from an alkyl cyanide using SnCl2/conc.HCl is known as ____________.
Which of the following alcohols needs acidic KMnO4 to convert it into aldehyde or ketone?
Which of the following is called as mandelonitrile?
Rosenmund reduction of ____________ yields benzaldehyde.
Identify the compound obtained by side chain chlorination of toluene and hydrolysed further.
The reaction in which methyl group on benzene ring is converted to aldehydic group is called ______.
The product of the reaction between dimethylcadmium and acetyl chloride is ____________.
Identify the compound A and Bin following reaction.
\[\ce{CH3Cl ->[KCN(alc)][\Delta] A ->[2H2O][HCl] B + NH4Cl}\]
Identify 'A' in the following reaction:
\[\begin{array}{cc}
\phantom{...........}\ce{O}\\
\phantom{...........}||\\
\ce{2A + (C6H5CH2)2 Cd -> 2CH3 - C - CH2 - C6H5 + CdCl2}\end{array}\]
Which among the following compounds is obtained when benzene is treated with CO and HCl in presence of catalyst anhydrous AlCl3 and Cu2Cl2 under high pressure?
Which of the following compounds does NOT undergo Friedel-Crafts reaction?
Identify 'A' in the following reaction.
\[\ce{A ->[H2][Pd-BaSO4] C6H5CHO + HCl}\]
Which of the following is obtained by hydrogenation of benzoyl chloride in presence of Pd on BaSO4?
Identify product A in the following reaction:
\[\ce{Acetyl chloride + Dibenzylcadmium -> A}\]
Chromyl chloride converts methyl group to a chromium complex, which on acid hydrolysis gives corresponding aldehyde. This reaction is called ____________.
Which of the following reaction is shown by alkynes?
Which of the following on heating with aqueous KOH, produces acetaldehyde?
Which reagent is used in Etard reaction?
Z is:
Ozonolysis of 2, 3 dimethyl but-2-ene, followed by decomposition by Zn dust and water gives ______.
Write Stephen reaction for the preparation of aldehyde.
How are the following compound obtained by hydration of alkenes?
Ethyl alcohol
Explain Rosenmund reduction reaction.
How acetone is prepared from nitriles using Grignard reagent?
Write the reaction of Ethanoyl chloride on diethylamine.