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Chemistry Set 1 2018-2019 HSC Science (General) 12th Standard Board Exam Question Paper Solution

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Chemistry [Set 1]
Marks: 70 Maharashtra State Board
HSC Science (General)
HSC Science (Electronics)
HSC Science (Computer Science)

Academic Year: 2018-2019
Date & Time: 27th February 2019, 11:00 am
Duration: 3h
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SECTION - A
[1]1

A compound used as pistachio flavour in ice cream is ___________

vanillin

acetophenone

muscone

butyraldehyde

Concept: undefined - undefined
Chapter: [0.12] Aldehydes, Ketones and Carboxylic Acids [12.01] Aldehydes and Ketones
[1]2

Oxidation states of scandium are ___________.

+1, +2

+1, +3

+2, + 3

+3, +4

Concept: undefined - undefined
Chapter: [8.01] D-block Elements
[1]3

In Van Arkel method for refining zirconium or titanium, the halogen used is __________.

fluorine

chlorine

bromine

iodine

Concept: undefined - undefined
Chapter: [0.06] General Principles and Processes of Isolation of Elements
[1]4

A system absorbs 6 kJ of heat and does 1.5 kJ of work on its surroundings. The change in internal energy is __________.

– 7.5 kJ

– 4.5 kJ

+4.5 kJ

+ 7.5 kJ

Concept: undefined - undefined
Chapter: [0.03] Chemical Thermodynamics and Energetic
[1]5

Write the molecular formula of noverstrol.

Concept: undefined - undefined
Chapter: [16.01] Chemicals in Medicines
[1]6

Write the number of hydroxyl groups present in α - D (+) -Glucopyranose (trans.)

Concept: undefined - undefined
Chapter: [14.01] Carbohydrates
[1]7

What is Nessler’s reagent ?

Concept: undefined - undefined
Chapter: [7.01] Group 15 Elements
[1]8

What is the ratio of octahedral holes to the number of anions in hexagonal closed packed structure?

Concept: undefined - undefined
Chapter: [0.01] Solid State
SECTION - B
[2]9

What are ethers?

Concept: undefined - undefined
Chapter: [11.03] Ethers

How are ethers classified?

Concept: undefined - undefined
Chapter: [11.03] Ethers
[2]10

What are antacids? 

Concept: undefined - undefined
Chapter: [16.01] Chemicals in Medicines

Write the main constituents of dettol.

Concept: undefined - undefined
Chapter: [11.02] Phenols
[2]11

Draw a neat, well labelled diagram of electrolytic cell for extraction of aluminium

Concept: undefined - undefined
Chapter: [0.06] General Principles and Processes of Isolation of Elements
[2]12
[2]12.A

How many faradays of electricity are required to produce 6 g of Mg from MgCl2?

Concept: undefined - undefined
Chapter: [0.04] Electrochemistry [0.05] Electrochemistry
OR
[2]12.B

The molar conductivity of 0.05 M BaCl2 solution at 25° C is 223Ω-1 cm2 mol-1. What is its conductivity?

Concept: undefined - undefined
Chapter: [0.05] Electrochemistry
[2]13

Derive van’t Hoff general solution equation.

Concept: undefined - undefined
Chapter: [0.02] Solutions [0.02] Solutions and Colligative Properties
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[2]14

Write the conditions for maximum work done by the system.

Concept: undefined - undefined
Chapter: [0.03] Chemical Thermodynamics and Energetic
[2]15

Write balanced chemical equation for the following :
Action of sodium metal on ethanol.

Concept: undefined - undefined
Chapter: [11.01] Alcohols

Write balanced chemical equation for the following :
Action of zinc dust on phenol.

Concept: undefined - undefined
Chapter: [11.02] Phenols
SECTION - C
[3]16

Write chemical reaction to prepare the following polymer: Teflon

Concept: undefined - undefined
Chapter: [0.15] Introduction to Polymer Chemistry [0.15] Polymers

Write chemical reaction to prepare the following polymer :
Nylon - 6

Concept: undefined - undefined
Chapter: [0.15] Polymers

Write chemical reaction to prepare the Dextron polymer:
Dextron

Concept: undefined - undefined
Chapter: [0.15] Polymers
[3]17

How is glucose prepared by commercial method? How is peptide linkage formed?

Concept: undefined - undefined
Chapter: [14.01] Carbohydrates
[3]18

Write a short note on Hofmann elimination

Concept: undefined - undefined
Chapter: [0.13] Amines
[3]19

What is the action of the following on ethyl bromide
alcoholic solution of potassium hydroxide.

Concept: undefined - undefined
Chapter: [10.01] Haloalkanes

What is the action of the following on ethyl bromide:
moist silver oxide

Concept: undefined - undefined
Chapter: [10.01] Haloalkanes

What is the action of the following on ethyl bromide:
silver acetate

Concept: undefined - undefined
Chapter: [10.01] Haloalkanes
[3]20

What is effective atomic number? Calculate effective atomic number of copper  ( Z = 29 ) in (Cu ( NH3)4)2+

Concept: undefined - undefined
Chapter: [0.09] Coordination Compounds
[3]21

Write chemical reactions for different steps in the manufacture of sulphuric acid by lead chamber process. Draw the structure of phosphorous pentachloride

Concept: undefined - undefined
Chapter: [7.02] Group 16 Elements
[3]22

Write Arrhenius equation. Derive an expression for temperature variations

Concept: undefined - undefined
Chapter:
[3]23

Write applications of electrochemical series.

Concept: undefined - undefined
Chapter: [0.05] Electrochemistry

Define electrochemical series. 

Concept: undefined - undefined
Chapter: [0.05] Electrochemistry
[3]24
[3]24.A

Calculate the work done in the following reaction at 50°C. State whether work is done on the system or by the system.
`"SO"_2("g") + 1/2"O"_(2("g")) rightarrow "SO"_(3("g"))`

Concept: undefined - undefined
Chapter: [0.03] Chemical Thermodynamics and Energetic
OR
[3]24.B

The standard enthalpy of combustion of formaldehyde Δ0H0 = -571 kJ. How much heat will be evolved in the formation of 22 g of CO2?

Concept: undefined - undefined
Chapter: [0.03] Chemical Thermodynamics and Energetic
[3]25

Define the following term:
isotonic solution

Concept: undefined - undefined
Chapter: [0.02] Solutions [0.02] Solutions and Colligative Properties

Define the following term:
hypertonic solution

Concept: undefined - undefined
Chapter: [0.02] Solutions [0.02] Solutions and Colligative Properties

Define the following term:
hypotonic solution

Concept: undefined - undefined
Chapter: [0.02] Solutions [0.02] Solutions and Colligative Properties
[3]26

Distinguish between crystalline solids and amorsphous solids.

Concept: undefined - undefined
Chapter: [0.01] Solid State [0.01] Solid State

Define Anisotropy.

Concept: undefined - undefined
Chapter: [0.01] Solid State [0.01] Solid State
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SECTION - D
[5]27 | Attempt any one
[1]27.A

Write the structure of Phenylmethanamine.

Concept: undefined - undefined
Chapter: [12.01] Aldehydes and Ketones
[4]27.B

Write chemical equation for the following:
Gatterman - Koch formylation

Concept: undefined - undefined
Chapter: [0.12] Aldehydes, Ketones and Carboxylic Acids [12.01] Aldehydes and Ketones

Write chemical equation for the following :
Rosenmund reduction

Concept: undefined - undefined
Chapter: [0.12] Aldehydes, Ketones and Carboxylic Acids [12.01] Aldehydes and Ketones

Write chemical equation for the following :
Fischer esterificatione

Concept: undefined - undefined
Chapter: [12.02] Carboxylic Acids

Write chemical equation for the following :
Hell - Vohlard - Zelinsky reaction

Concept: undefined - undefined
Chapter: [12.02] Carboxylic Acids
OR
[1]27.C

What are amines?

Concept: undefined - undefined
Chapter: [12.01] Aldehydes and Ketones
[4]27.D

How will you convert calcium acetate to acetaldehyde?

Concept: undefined - undefined
Chapter: [0.12] Aldehydes, Ketones and Carboxylic Acids [12.01] Aldehydes and Ketones

How will you convert acetone to acetone cyanohydrin?

Concept: undefined - undefined
Chapter: [12.01] Aldehydes and Ketones

How will you convert sodium acetate to methane?

Concept: undefined - undefined
Chapter: [12.01] Aldehydes and Ketones

How will you convert benzoic acid to m-bromobenzoic acid?

Concept: undefined - undefined
Chapter: [12.01] Aldehydes and Ketones
[5]28 | Attempt any one.
[1]28.A

Define Enantiomers.

Concept: undefined - undefined
Chapter: [10.01] Haloalkanes [10.02] Haloarenes
[4]28.B

How is potassium dichromate prepared from chrome iron ore?

Concept: undefined - undefined
Chapter: [8.01] D-block Elements
OR
[1]28.C

What is Grignard reagent?

Concept: undefined - undefined
Chapter: [10.02] Haloarenes
[4]28.D

Explain the position of actinoids in the periodic table.
What is the action of sulphur on lanthanoids? Calculate the magnetic moment of divalent ion in aqueous solution it its atomic number is 24.

Concept: undefined - undefined
Chapter: [8.01] D-block Elements
[5]29 | Attempt any one
[1]29.A

The rate of a first order reaction, A →B is 5.4 ×10-6 
Ms-1when [A] is 0.3M. Calculate the rate constant of the reaction.

Concept: undefined - undefined
Chapter:
[4]29.B

Explain the following properties of group 16 elements :
1) Electro negativity
2) Melting and boiling points
3) Metallic character
4) Allotropy

Concept: undefined - undefined
Chapter: [7.02] Group 16 Elements
OR
[1]29.C

The half life period of a first order reaction is 6. 0 h . Calculate the rate constant

Concept: undefined - undefined
Chapter: [0.05] Chemical Kinetics [0.06] Chemical Kinetics
[4]29.D

What are oxides?  Write different types of oxides with one example each.

Concept: undefined - undefined
Chapter: [7.02] Group 16 Elements

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