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प्रश्न
A white solid A when heated with sodium hydroxide solution, gives a pungent gas B, which turns red litmus blue. The solid, when dissolved in dilute nitric acid and treated with silver nitrate gives a white precipitate of C which is soluble in an ammonia solution.
उत्तर
C is silver chloride which is soluble in ammonia.
Pungent smelling gas B is ammonia.
White solid A is ammonium chloride.
\[\ce{NH4Cl(s) ->[NaOH] NH3(g) + H2O + NaCl}\]
\[\ce{NH3(g) ->[Red litmus] blue litmus}\]
\[\ce{\underset{\text{A}}{NH4Cl(s)} ->[AgNO3][HNO3] \underset{\text{C}}{AgCl(s)}}\]
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संबंधित प्रश्न
Identify the cations in the following case:
NaOH solution, when added to the Solution (A), gives a reddish brown precipitate
What do you observe when caustic soda solution is added to the following solution, first a little and then in excess:
ZnSO4
Write a balanced equation for this reaction.
Name the chloride of a metal which is soluble in excess of ammonium hydroxide. Write equation for the same.
Distinguish by adding:
(a) sodium hydroxide solution and
(b) Ammonium hydroxide solution to
(i) Calcium salt solution and lead salt solution
(ii) Lead salt solution and ferrous salt solution
(iii) copper salt solution and ferrous salt solution
(iv) Fe (II) salt solution and Fe (III) Salt solution
(v) Ferrous nitrate and lead nitrate
Using sodium hydroxide solution, how will you distinguish:
Lead hydroxide from magnesium hydroxide.
Sodium hydroxide solution is added to the solutions containing the ions mentioned in List X. List Y gives the details of the precipitate. Match the ions with their coloured precipitates.
| List X | List Y |
| (i) Pb2+ | (A) Reddish Brown |
| (ii) Fe2+ | (B) White insoluble inexcess |
| (iii) Zn2+ | (C) Dirty green |
| (iv) Fe3+ | (D) White soluble in excess |
| (v) Cu2+ | (E) White soluble in excess |
| (vi) Ca2+ | (F) Blue |
Distinguish by adding:
Sodium hydroxide solution and ammonium hydroxide solution to copper salt solution and ferrous salt solution.
Distinguish by adding:
Sodium hydroxide solution and ammonium hydroxide solution to Fe(II) salt solution and Fe(III) salt solution.
Identify the cation in the following case:
Sodium hydroxide solution when added to Solution C gives a white precipitate which is insoluble in excess of sodium hydroxide solution.
Aqueous lead (II) nitrate can be distinguished from aqueous zinc nitrate by adding any of the following solutions in excess, except:
