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प्रश्न
Among the elements \[\ce{B, Al, C}\] and \[\ce{Si}\], which element has the highest first ionisation enthalpy?
उत्तर
C has the highest ionization energy among the given elements as along the period ionization enthalpy increases whereas it decreases down the group.
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संबंधित प्रश्न
Energy of an electron in the ground state of the hydrogen atom is –2.18 × 10–18 J. Calculate the ionization enthalpy of atomic hydrogen in terms of J mol–1.
Hint: Apply the idea of mole concept to derive the answer.
Among the second period elements the actual ionization enthalpies are in the
order Li < B < Be < C < O < N < F < Ne.
Explain why Be has higher ΔiH than B?
The first ionization enthalpy values (in kJmol–1) of group 13 elements are:-
B | Al | Ga | In | Tl |
801 | 577 | 579 | 558 | 589 |
How would you explain this deviation from the general trend?
Would you expect the first ionization enthalpies for two isotopes of the same element to be the same or different? Justify your answer.
Nitrogen has positive electron gain enthalpy whereas oxygen has negative. However, oxygen has lower ionisation enthalpy than nitrogen. Explain.
Explain the deviation in ionisation enthalpy of some elements from the general trend by using the given figure.
Explain the following:
Ionisation enthalpy decrease in a group from top to bottom?
Assertion (A): Generally, ionisation enthalpy increases from left to right in a period.
Reason (R): When successive electrons are added to the orbitals in the same principal quantum level, the shielding effect of inner core of electrons does not increase very much to compensate for the increased attraction of the electron to the nucleus.
For the gaseous reaction, \[\ce{K_{(g)} + F_{(g)} -> K^+_{ (g)} + F^-_{ (g)}}\], ΔH was calculated to be 19 kcal/mol under conditions where the cations and anions were prevented by electrostatic separation from combining with each other. The ionisation energy of K is 4.3 eV. The electron affinity of F is ______. (in eV)
Which of the following atoms has the highest first ionization energy?