Advertisements
Advertisements
प्रश्न
Calculate the mass of ascorbic acid (molecular mass = 176 g/mol) that should be dissolved in 155 g of acetic acid to cause a depression of the freezing point by 1.15 K. Assume that ascorbic acid does not dissociate or associate in the solution. (Kf for acetic acid = 3.9 K kg/mol)
उत्तर
Mass of acetic acid (ω1) = 155 gm
Molar mass of ascorbic acid = 176 g mol-1
Lowering melting point, ΔTf = 1.15 K
`Delta "T"_"f" = ("K"_"f" xx 1000 xx omega_2)/("M"_2 xx omega_1)`
`omega_2 = (1.15 xx 176 xx 155)/(3.9 xx 1000)`
`omega_2 = 8.044` gm
Hence, 8.044 g of ascorbic acid is needed to be dissolved.
APPEARS IN
संबंधित प्रश्न
An aqueous solution of urea freezes at – 0.186°C, Kf for water = 1.86 K kg mo1–1, Kb for water = 0.512 K kg mo1–1. The boiling point of urea solution will be:
Answer the following question:
Why the freezing point depression (ΔTf) of 0.4 M NaCl solution is nearly twice than that of 0.4 M glucose solution?
Obtain the relationship between freezing point depression of a solution containing nonvolatile-nonelectrolyte solute and its molar mass.
A 5% aqueous solution (by mass) of cane sugar (molar mass 342 g mol-1) has a freezing point of 271 K. Calculate the freezing point of 5% aqueous glucose solution.
Write the effect of dissolution of a nonvolatile solute on the freezing point of solvent.
Calculate total moles after dissociation in 0.1 M KCl solution and 0.05 M aluminium sulphate solution. Hence, decide which of the two solutions will have higher freezing point depression.
Explain with vapour pressure-temperature curves that the freezing point of a solvent is lowered by dissolving a nonvolatile solute into it. Give reason for such lowering of freezing of solvent.
Write the SI unit of the cryoscopic constant.
Calculate the mass of compound to be dissolved in 75g of benzene to lower its freezing point by 0.48 K. (Given: Kf = 0.512 K kg mol-1 and molar mass = 256g mol-1)
Ethylene glycol is used as an antifreeze agent. Calculate the amount of ethylene glycol to be added to four kilogram of water to prevent it from freezing at −6°C.
(Kf of water = 1.86 K kg mol-1 ) Assume that ethylene glycol (CH2OH.CH2OH) does not dissociate or associate in aqueous solution.