Advertisements
Advertisements
प्रश्न
During nuclear explosion, one of the products is 90Sr with half-life of 28.1 years. If 1μg of 90Sr was absorbed in the bones of a newly born baby instead of calcium, how much of it will remain after 10 years and 60 years if it is not lost metabolically.
उत्तर
`t_(1/2)` 90Sr = 28.1 yr, k = `0.693/28.1 "yr"^-1`
Now, t = `2.303/"k" log "a"/(("a" - "x"))` ...(a = 1 µg)
After 10 years, 10 = `(2.303 xx 28.1)/0.693 log 1/(("a" - "x"))`
The remaining amount of Sr = (a − x) = 0.7814 µg
After 60 years, 60 = `(2.303 xx 28.1)/0.693 log 1/(("a" - "x"))`
The remaining amount of Sr = 0.2278 µg
APPEARS IN
संबंधित प्रश्न
The half-life for radioactive decay of 14C is 5730 years. An archaeological artifact containing wood had only 80% of the 14C found in a living tree. Estimate the age of the sample.
The experimental data for decomposition of N2O5
\[\ce{2N2O5 -> 4NO2 + O2}\] in gas phase at 318K are given below:
t/s | 0 | 400 | 800 | 1200 | 1600 | 2000 | 2400 | 2800 | 3200 |
102 × [N2O5]/mol L−1 | 1.63 | 1.36 | 1.14 | 0.93 | 0.78 | 0.64 | 0.53 | 0.43 | 0.35 |
- Plot [N2O5] against t.
- Find the half-life period for the reaction.
- Draw a graph between log [N2O5] and t.
- What is the rate law?
- Calculate the rate constant.
- Calculate the half-life period from k and compare it with (ii).
The unit of rate constant for zero order reaction is _______.
(A) t–1
(B) mol dm–3 t–1
(C) mol–1 dm3 t–1
(D) mol–2 dm6 t–1
The half life period of a first order reaction is 6. 0 h . Calculate the rate constant
In a first-order reaction A → product, 80% of the given sample of compound decomposes in 40 min. What is the half-life period of the reaction?
After 2 hours, a radioactive substance becomes `(1/16)^"th"` of original amount. Then the half life ( in min) is
The half life of the homogeneous gaseous reaction \[\ce{SO2Cl2 -> SO2 + Cl2}\] which obeys first order kinetics is 8.0 minutes. How long will it take for the concentration of SO2Cl2 to be reduced to 1% of the initial value?
Read the passage given below and answer the following question.
Are there nuclear reactions going on in our bodies? There are nuclear reactions constantly occurring in our bodies, but there are very few of them compared to the chemical reactions, and they do not affect our bodies much. All of the physical processes that take place to keep a human body running are chemical processes. Nuclear reactions can lead to chemical damage, which the body may notice and try to fix. The nuclear reaction occurring in our bodies is radioactive decay. This is the change of a less stable nucleus to a more stable nucleus. Every atom has either a stable nucleus or an unstable nucleus, depending on how big it is and on the ratio of protons to neutrons. The ratio of neutrons to protons in a stable nucleus is thus around 1 : 1 for small nuclei (Z < 20). Nuclei with too many neutrons, too few neutrons, or that are simply too big are unstable. They eventually transform to a stable form through radioactive decay. Wherever there are atoms with unstable nuclei (radioactive atoms), there are nuclear reactions occurring naturally. The interesting thing is that there are small amounts of radioactive atoms everywhere: in your chair, in the ground, in the food you eat, and yes, in your body. The most common natural radioactive isotopes in humans are carbon-14 and potassium-40. Chemically, these isotopes behave exactly like stable carbon and potassium. For this reason, the body uses carbon-14 and potassium-40 just like it does normal carbon and potassium; building them into the different parts of the cells, without knowing that they are radioactive. In time, carbon-14 atoms decay to stable nitrogen atoms and potassium-40 atoms decay to stable calcium atoms. Chemicals in the body that relied on having a carbon-14 atom or potassium-40 atom in a certain spot will suddenly have a nitrogen or calcium atom. Such a change damages the chemical. Normally, such changes are so rare, that the body can repair the damage or filter away the damaged chemicals. The natural occurrence of carbon-14 decay in the body is the core principle behind carbon dating. As long as a person is alive and still eating, every carbon-14 atom that decays into a nitrogen atom is replaced on average with a new carbon-14 atom. But once a person dies, he stops replacing the decaying carbon-14 atoms. Slowly the carbon-14 atoms decay to nitrogen without being replaced, so that there is less and less carbon-14 in a dead body. The rate at which carbon-14 decays is constant and follows first order kinetics. It has a half-life of nearly 6000 years, so by measuring the relative amount of carbon-14 in a bone, archeologists can calculate when the person died. All living organisms consume carbon, so carbon dating can be used to date any living organism, and any object made from a living organism. Bones, wood, leather, and even paper can be accurately dated, as long as they first existed within the last 60,000 years. This is all because of the fact that nuclear reactions naturally occur in living organisms. |
Suppose an organism has 20 g of Carbon-14 at its time of death. Approximately how much Carbon-14 remains after 10,320 years? (Given antilog 0.517 = 3.289)
Read the passage given below and answer the following question.
Are there nuclear reactions going on in our bodies? There are nuclear reactions constantly occurring in our bodies, but there are very few of them compared to the chemical reactions, and they do not affect our bodies much. All of the physical processes that take place to keep a human body running are chemical processes. Nuclear reactions can lead to chemical damage, which the body may notice and try to fix. The nuclear reaction occurring in our bodies is radioactive decay. This is the change of a less stable nucleus to a more stable nucleus. Every atom has either a stable nucleus or an unstable nucleus, depending on how big it is and on the ratio of protons to neutrons. The ratio of neutrons to protons in a stable nucleus is thus around 1 : 1 for small nuclei (Z < 20). Nuclei with too many neutrons, too few neutrons, or that are simply too big are unstable. They eventually transform to a stable form through radioactive decay. Wherever there are atoms with unstable nuclei (radioactive atoms), there are nuclear reactions occurring naturally. The interesting thing is that there are small amounts of radioactive atoms everywhere: in your chair, in the ground, in the food you eat, and yes, in your body. The most common natural radioactive isotopes in humans are carbon-14 and potassium-40. Chemically, these isotopes behave exactly like stable carbon and potassium. For this reason, the body uses carbon-14 and potassium-40 just like it does normal carbon and potassium; building them into the different parts of the cells, without knowing that they are radioactive. In time, carbon-14 atoms decay to stable nitrogen atoms and potassium-40 atoms decay to stable calcium atoms. Chemicals in the body that relied on having a carbon-14 atom or potassium-40 atom in a certain spot will suddenly have a nitrogen or calcium atom. Such a change damages the chemical. Normally, such changes are so rare, that the body can repair the damage or filter away the damaged chemicals. The natural occurrence of carbon-14 decay in the body is the core principle behind carbon dating. As long as a person is alive and still eating, every carbon-14 atom that decays into a nitrogen atom is replaced on average with a new carbon-14 atom. But once a person dies, he stops replacing the decaying carbon-14 atoms. Slowly the carbon-14 atoms decay to nitrogen without being replaced, so that there is less and less carbon-14 in a dead body. The rate at which carbon-14 decays is constant and follows first order kinetics. It has a half-life of nearly 6000 years, so by measuring the relative amount of carbon-14 in a bone, archeologists can calculate when the person died. All living organisms consume carbon, so carbon dating can be used to date any living organism, and any object made from a living organism. Bones, wood, leather, and even paper can be accurately dated, as long as they first existed within the last 60,000 years. This is all because of the fact that nuclear reactions naturally occur in living organisms. |
Approximately how old is a fossil with 12 g of Carbon-14 if it initially possessed 32 g of Carbon-14? (Given log 2.667 = 0.4260)
Half life (t1/2) and completion time (T) of the zero order reaction are- (K = 0.001 mol/litre/sec and a = 1 M.)
A first-order reaction takes 69.3 min for 50% completion. What is the time needed for 80% of the reaction to get completed? (Given: log 5 = 0.6990, log 8 = 0.9030, log 2 = 0.3010)
The rate of a first order reaction is 0.04 mol litre-1 s-1 at 10 minutes and 0.03 mol litre-1 sec-1 at 20 minutes after initiation. The half-life of the reaction is ______ min.
For the given first order reaction A → B the half life of the reaction is 0.3010 min. The ratio of the initial concentration of reactant to the concentration of reactant at time 2.0 min will be equal to ______. (Nearest integer)
A reaction has a half-life of 1 min. The time required for 99.9% completion of the reaction is ______ min.
(Round off to the nearest integer).
[Use: In 2 = 0.69; In 10 = 2.3]
Assertion (A): The half-life of a reaction is the time in which the concentration of the reactant is reduced to one-half of its initial concentration.
Reason (R): In first-order kinetics, when the concentration of reactant is doubled, its half-life is doubled.
The unit of rate constant of zero order reaction is ______.
Show that the half-life of zero order reaction is `t_(1/2) = ([A]_0)/(2k)`.
Calculate the half-life of a first order reaction from the rate constant given below:
4 year−1