Advertisements
Advertisements
प्रश्न
Explain in brief, the significance of the azimuthal quantum number.
उत्तर
- Azimuthal quantum number is also known as the subsidiary quantum number and is represented by the letter l.
- It represents the subshell to which the electron belongs. It also defines the shape of the orbital that is occupied by the electron.
- Its value depends upon the value of principal quantum number ‘n’. It can have only positive values between 0 and (n − 1).
- Atomic orbitals with the same value of ‘n’ but different values of ‘l’ constitute a subshell belonging to the shell for the given ‘n’. The azimuthal quantum number gives the number of subshells in a principal shell. The subshells have l to be 0, 1, 2, 3 … which are represented by symbols s, p, d, f, … respectively.
Principal shell Value of n Permissible value of l Possible subshell Number of subshells in shell K 1 0 s 1 L 2 0, 1 s, p 2 M 3 0, 1, 2 s, p, d 3 N 4 0, 1, 2, 3 s, p, d, f 4
APPEARS IN
संबंधित प्रश्न
Using s, p, d notations, describe the orbital with the following quantum numbers n = 1, l = 0.
Using s, p, d notations, describe the orbital with the following quantum numbers n = 3; l =1.
Choose the correct option.
Principal Quantum number describes -
Explain the anomalous behaviour of copper.
Write orbital notations for the electron in orbitals with the following quantum numbers.
n = 4, l = 2
Draw shapes of 2s orbitals.
Using the concept of quantum numbers, calculate the maximum numbers of electrons present in the ‘M’ shell. Give their distribution in shells, subshells, and orbitals.
Indicate the number of unpaired electrons in \[\ce{Si}\] (Z = 14).
Which mineral among the following contains vanadium in it?
Which one of the following orders is CORRECT in case of energy of the given subshells?
P: n = 4; l = 3
Q: n = 5; I = 1
R: n = 5; l = 0
S: n = 4; l = 2
How many electrons in 19K have n = 3, l = 1?
The three electrons have the following set of quantum numbers:
X = 6, 1, −1, `+1/2`
Y = 6, 0, 0, `+1/2`
Z = 5, 1, 0, `+1/2`
Identify the CORRECT statement.
Which one of the following is NOT possible?
Which of the following options does not represent ground state electronic configuration of an atom?
Number of angular nodes for 4d orbital is ______.
The pair of ions having same electronic configuration is ______.
Which of the following sets of quantum numbers are correct?
| `n` | `l` | `m_l` | |
| (i) | 1 | 1 | +2 |
| (ii) | 2 | 1 | +1 |
| (iii) | 3 | 2 | –2 |
| (iv) | 3 | 4 | –2 |
In which of the following pairs, the ions are iso-electronic?
(i) \[\ce{Na^{+}, Mg^{2+}}\]
(ii) \[\ce{Al3^{+}, O-}\]
(iii) \[\ce{Na+ , O2-}\]
(iv) \[\ce{N3-, Cl-}\]
Which of the following statements concerning the quantum numbers are correct?
(i) Angular quantum number determines the three dimensional shape of the orbital.
(ii) The principal quantum number determines the orientation and energy of the orbital.
(iii) Magnetic quantum number determines the size of the orbital.
(iv) Spin quantum number of an electron determines the orientation of the spin of electron relative to the chosen axis.
Which of the following orbitals are degenerate?
3dxy, 4dxy 3dz2, 3dyz, 4dyz, 4dz2
The arrangement of orbitals on the basis of energy is based upon their (n + l) value. Lower the value of (n + l), lower is the energy. For orbitals having same values of (n + l), the orbital with lower value of n will have lower energy.
Based upon the above information, arrange the following orbitals in the increasing order of energy.
1s, 2s, 3s, 2p
The arrangement of orbitals on the basis of energy is based upon their (n + l) value. Lower the value of (n + l), lower is the energy. For orbitals having same values of (n + l), the orbital with lower value of n will have lower energy.
Based upon the above information, solve the questions given below:
Which of the following orbitals has the lowest energy?
4d, 4f, 5s, 5p
What is the difference between the terms orbit and orbital?
Choose the INCORRECT statement
Which of the following is the correct plot for the probability density ψ2 (r) as a function of distance 'r' of the electron from the nucleus for 2s orbitals?
Which of the following is not the permissible arrangement of electrons in an atom?
