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F-Be-F is a liner molecule but H-O-H is angular. Explain. - Chemistry

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प्रश्न

F-Be-F is a liner molecule but H-O-H is angular. Explain.

थोडक्यात उत्तर

उत्तर

  1. In the BeF2 molecule, the central beryllium atom undergoes sp hybridization giving rise to two sp hybridized orbitals placed diagonally opposite with an angle of 180°. Thus, F-Be-F is a linear molecule.
  2. In the H2O molecule, the central oxygen atom undergoes sp3 hybridization giving rise to four sp3 hybridized orbitals directed towards four corners of a tetrahedron. There are two lone pairs of electrons in two of the sp3 hybrid orbitals of oxygen. The lone pair-lone pair repulsion distorts the structure. Hence, H-O-H is angular or V-shaped.
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Parameters of Covalent Bond
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पाठ 5: Chemical Bonding - Exercises [पृष्ठ ७९]

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बालभारती Chemistry [English] 11 Standard
पाठ 5 Chemical Bonding
Exercises | Q 3. (K) | पृष्ठ ७९

संबंधित प्रश्‍न

Select and write the most appropriate alternatives from the given choices.

The angle between the two covalent bonds is minimum in:


In Ammonia molecule the bond angle is 107° and in water molecule it is 104°35', although in both the central atoms are sp3 hybridized Explain.


Write the geometry and bond angle present in ammonia.


In the case of bond formation in Acetylene molecule: How many covalent bonds are formed?


In the case of bond formation in Acetylene molecule: State number of sigma and pi bonds formed.


In the case of bond formation in Acetylene molecule: Name the type of Hybridization.


Define Bond Length


Predict the shape and bond angles in the following molecule:

CF4


Predict the shape and bond angles in the following molecule:

NF3


Predict the shape and bond angles in the following molecule:

HCN


Using data from the Table, answer the following:

Examples C2H6 Ethane C2H4 Ethene C2H2 Ethyne
Structure

\[\begin{array}{cc} \backslash \phantom{......}/\phantom{.}\\ \ce{—C – C —}\\  /\phantom{......}\backslash\phantom{.}\end{array}\]

\[\begin{array}{cc} \backslash \phantom{......}/\\ \ce{C \text{=} C}\\  /\phantom{......}\backslash\end{array}\]

\[\ce{- C ≡ C -}\]
Type of bond between carbons single double triple
Bond length (nm) 0.154 0.134 0.120
Bond Enthalpy kJ mol-1 348 612 837
  1. What happens to the bond length when unsaturation increases?
  2. Which is the most stable compound?
  3. Indicate the relationship between bond strength and Bond enthalpy.
  4. Comment on the overall relation between Bond length, Bond Enthalpy, and Bond strength and stability.

Write the formula to calculate the bond order of molecule.


The CORRECT order of C-X bond polarity is ____________.


In gas phase H-O-O-H bond angle in H2O2 is ______.


What is the value of C-O-H bond angle in CH3_OH?


Which of following bonds has maximum bond length?


What is the H-S-H bond angle in H2S?


The hybridization and bond angle in BeCl2 molecule are ____________ respectively.


Consider the reactions.

\[\ce{C_{(s)} + 2H2_{(g)} -> CH4_{(g)}}\], ΔH = −x kcal

\[\ce{C_{(g)} + 4H_{(g)} -> CH4_{(g)}}\], ΔH = −x1 kcal

\[\ce{CH4_{(g)} -> CH3_{(g)} + H_{(g)}}\], ΔH = +y kcal

The average C-H bond enthalpy is:


The bond angle is minimum in ____________.


Identify the CORRECT option.


Which of the following is INCORRECTLY matched?


What is the bond order of B2 molecule?


Why is bond order of Be2 molecule zero?

(Nb = bonding electrons, Na = antibonding electrons)


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