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प्रश्न
Give reasons for the following observation:
Aniline is acetylated before nitration reaction.
उत्तर
Aniline is acetylated, before the nitration reaction in order to avoid the formation of tarry oxidation products and protect the amino group, so that p-nitro derivative can be obtained as major product.
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संबंधित प्रश्न
Write the structures of main products when aniline reacts with the following reagents :
(CH3CO)2O/pyridine
What is the action of acetic anhydride on diethylamine?
What is the action of the following reagents on aniline?
Acetic anhydride
Illustrate the following reactions giving suitable example in each case
Acetylation of amines
How will you convert the following?
Aniline into N−phenylethanamide
In the nitration of benzene using a mixture of conc. \[\ce{H2SO4}\] and conc. \[\ce{HNO3}\], the species which initiates the reaction is ______.
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Reason: Sulphonyl group attached to nitrogen atom is strong electron-withdrawing group.
When bromination of aniline is carried out by protecting – NH2. The major product is
Give reasons for the following observation:
Aniline does not react with methyl chloride in the presence of anhydrous AlCl3 catalyst.
How can the activating effect of the −NH2 group in aniline be controlled?
