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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

How the following conversion can be carried out? Chlorobenzene to p-nitrophenol - Chemistry

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प्रश्न

How the following conversion can be carried out?

Chlorobenzene to p-nitrophenol

रासायनिक समीकरणे/रचना

उत्तर

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पाठ 10: Haloalkanes and Haloarenes - Exercises [पृष्ठ ३१२]

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एनसीईआरटी Chemistry [English] Class 12
पाठ 10 Haloalkanes and Haloarenes
Exercises | Q 19.15 | पृष्ठ ३१२

संबंधित प्रश्‍न

Chlorobenzene is extremely less reactive towards a nucleophilic substitution reaction. Give two reasons for the same.


Write the final product(s) in each of the following reactions:


The presence of nitro group (−NO2) at o/p positions increases the reactivity of haloarenes towards nucleophilic substitution reactions.


Write the product formed on reaction of D-glucose with Br2 water.


What is Grignard reagent?


Write chemical equation in support of your answer. 
 Out of   Cl and  CH2- Cl,  which one is more reactive towards nucleophilic substitution reaction and why? 


Assertion: Presence of a nitro group at ortho or para position increases the reactivity of haloarenes towards nucleophilic substitution.

Reason: Nitro group, being an electron-withdrawing group decreases the electron density over the benzene ring.


Which of the following compounds will give racemic mixture on nucleophilic substitution by \[\ce{OH-}\] ion?

(a) \[\begin{array}{cc}
\phantom{}\ce{CH3 - CH - Br}\\
\phantom{}|\\
\phantom{....}\ce{C2H5}\phantom{}
\end{array}\]

 

(b) \[\begin{array}{cc}
\phantom{..}\ce{Br}\\
\phantom{}|\\
\phantom{}\ce{CH3 - C - CH3}\\
\phantom{}|\\
\phantom{....}\ce{C2H5}\phantom{}
\end{array}\]

 

(c) \[\begin{array}{cc}
\phantom{....}\ce{CH3 - CH - CH2Br}\\
\phantom{}|\\
\phantom{....}\ce{C2H5}\phantom{}
\end{array}\]


Arrange the following compounds in increasing order of rate of reaction towards nucleophilic substitution.

(a)
(b)
(c)

Arrange the following compounds in increasing order of rate of reaction towards nucleophilic substitution.

(a)
(b)
(c)

Arrange the following compounds in increasing order of rate of reaction towards nucleophilic substitution.

(a)
(b)
(c)

Haloarenes are less reactive than haloalkanes and haloalkenes. Explain.


Assertion: Chlorobenzene is resistant to nucleophilic substitution reaction at room temperature.

Reason (R): C–Cl bond gets weaker due, to resonance.


Why haloarenes are not reactive towards nucleophilic substitution reaction? Give two reactions.


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