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प्रश्न
Identify ‘A' and ‘B’ in the following reaction :
C6H5MgBr + C02 `(`> ‘A’ `(PCl_5)/()`> ‘B’
उत्तर
C6H5MgBr + CO2`"Dry ether"/("H"^+ /(H_2O))`> C6H5COOH `"PCl"/`> C6H5COCl
Phenyl Benzoic acid Benzoyl magnesium (A) chloride bromide (B)
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संबंधित प्रश्न
Predict the products of the following reactions:
Name the reagents used in the following reactions:
Show how the following compound can be converted to benzoic acid.
Ethylbenzene
Show how the following compound can be converted to benzoic acid.
Bromobenzene
Show how the following compound can be converted to benzoic acid.
Phenylethene (Styrene)
Predict the products formed when cyclohexanecarbaldehyde reacts with the following reagent.
Tollens’ reagent
An organic compound (A) (molecular formula C8H16O2) was hydrolysed with dilute sulphuric acid to give a carboxylic acid (B) and an alcohol (C). Oxidation of (C) with chromic acid produced (B). (C) on dehydration gives but-1-ene. Write equations for the reactions involved.
How will you prepare the given compound from benzene? You may use any inorganic reagent and any organic reagent having not more than one carbon atom.
m-Nitrobenzoic acid
How will you prepare the given compound from benzene? You may use any inorganic reagent and any organic reagent having not more than one carbon atom.
p-Nitrobenzoic acid
How will you prepare the given compound from benzene? You may use any inorganic reagent and any organic reagent having not more than one carbon atom.
Phenylacetic acid
How will you bring about the following conversion in not more than two steps?
Benazaldehyde to α-Hydroxyphenylacetic acid
How is methoxy benzene prepared from carbolic acid?
Name the reagents used in the following reactions:
What is the action of following reagents on glucose?
1. Bromine water
2. Hydroxylamine
Which is the most suitable reagent for the following conversion?
\[\begin{array}{cc}
\phantom{....................}\ce{O}\phantom{.....................................}\ce{O}\phantom{.}\\
\phantom{....................}||\phantom{......................................}||\phantom{.}\\
\phantom{}\ce{CH3 - CH = CH - CH2 - C - CH3 -> CH3 - CH = CH - CH2 - C - OH}\phantom{.}
\end{array}\]
Through which of the following reactions number of carbon atoms can be increased in the chain?
(i) Grignard reaction
(ii) Cannizaro’s reaction
(iii) Aldol condensation
(iv) HVZ reaction
Assertion: Aldehydes and ketones, both react with Tollen’s reagent to form silver mirror.
Reason: Both, aldehydes and ketones contain a carbonyl group.
Substitution of one alkyl group by replacing hydrogen of primary amines
Which of the following substance produced acetaldehyde on dry distillation?
Match List - I with List - II.
| List - I | List - II | ||
| (a) |  \[\ce{->[CO,HCl][Anhyd. AlCl3/CuCl]}\] |
(i) | Hell-Volhard-Zelinsky reaction |
| (b) |
\[\begin{array}{cc}
\ce{O}\phantom{.................}\\ ||\phantom{.................}\\ \ce{R - C - CH3 + NaOX ->} \end{array}\] |
(ii) | Gattermann-Koch reaction |
| (c) | \[\ce{R - CH2 - OH + R'COOH ->[Conc. H2SO4]}\] | (iii) | Haloform reaction |
| (d) | \[\ce{R - CH2COOH ->[(i) X2/Red P][(ii) H2O]}\] | (iv) | Esterification |
Choose the correct answer from the options given below.
The end product Y in the sequence of reaction:
\[\ce{RX ->[CN^-] X ->[NaOH] Y}\] is:
A compound 'X' with molecular formula C3H8O can be oxidised to a compound 'Y' with the molecular formula C3H6O2 'X' is most likely to be ______.
Fill in the blanks by choosing the appropriate words from those given in the brackets:
[stable, low, aldehyde, unstable, 6, 4, ethane, Clemmensen’s, 2, 3, carboxylic acid, high, propane, Rosenmund's]
The primary alcohols are easily oxidised first into ______ and then into ______.
