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प्रश्न
Identify the compounds A, X and Z in the following reactions:
\[\ce{X ->[Δ][370 K] HBO2 ->[Δ][> 370 K] Z}\]
उत्तर
\[\ce{\underset{(X)}{H3BO3} ->[Δ, 370 K] \underset{Metaboric acid}{HBO2} + H2O}\]
\[\ce{4HBO2 ->[Δ, 370 K][-H2O] \underset{Tetraboric acid}{[H2B4O7]} ->[Read heat] \underset{Boric trioxide (Z)}{2B2O3} + H2O}\]
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संबंधित प्रश्न
What do you understand by inert pair effect?
A compound X, of boron reacts with NH3 on heating to give another compound Y which is called inorganic benzene. The compound X can be prepared by treating BF3 with Lithium aluminium hydride. The compounds X and Y are represented by the formulas.
Which of the following statements are correct. Answer on the basis of Figure.
(i) The two birdged hydrogen atoms and the two boron atoms lie in one plane;
(ii) Out of six B – H bonds two bonds can be described in terms of 3 centre 2-electron bonds.
(iii) Out of six B – H bonds four B – H bonds can be described in terms of 3 centre 2 electron bonds;
(iv) The four-terminal B – H bonds are two centre-two electron regular bonds.
Explain the following:
Electron gain enthalpy of chlorine is more negative as compared to fluorine.
Complete the following chemical equations:
\[\ce{Z + 3 LiAlH4 -> X + 3LiF + 3AlF_3}\]
\[\ce{X + 6H2 -> Y + 6H2}\]
\[\ce{3X + 3O2 ->[Δ] B2O3 + 3H2O}\]
Match the species given in Column I with the hybridisation given in Column II.
| Column I | Column II |
| (i) Boron in [B(OH)4]– | (a) sp2 |
| (ii) Aluminium in [Al(H2O)6]3+ | (b) sp3 |
| (iii) Boron in B2H6 | (c) sp3d2 |
| (iv) Carbon in Buckminsterfullerene | |
| (v) Silicon in \[\ce{SiO^{4-}4}\] | |
| (vi) Germanium in [GeCl6]2– |
Describe the general trends in the following properties of the elements in Groups 13 and 14.
Ionisation enthalpy
Describe the general trends in the following properties of the elements in Groups 13 and 14.
Oxidation states
Describe the general trends in the following properties of the elements in Groups 13 and 14.
Nature of halides
A group 13 element ‘X’ reacts with chlorine gas to produce a compound XCl3. XCl3 is electron deficient and easily reacts with NH3 to form \[\ce{Cl3X –> NH3}\] adduct; however, XCl3 does not dimerize X is ______.
