मराठी

Explain the following: Electron gain enthalpy of chlorine is more negative as compared to fluorine. - Chemistry

Advertisements
Advertisements

प्रश्न

Explain the following:

Electron gain enthalpy of chlorine is more negative as compared to fluorine.

टीपा लिहा

उत्तर

Due to small size, the electron-electron repulsions in the relatively compact 2p-subshell of F are quite strong and hence the incoming electron is not accepted with the same ease as in case of bigger Cl atom where repulsions are comparatively weak. Thus, electron gain enthalpy of chlorine is more negative as compared to that of fluorine.

shaalaa.com
Group 13 Elements - The Boron Family
  या प्रश्नात किंवा उत्तरात काही त्रुटी आहे का?
पाठ 11: The p-block Elements - Multiple Choice Questions (Type - I) [पृष्ठ १३८]

APPEARS IN

एनसीईआरटी एक्झांप्लर Chemistry [English] Class 11
पाठ 11 The p-block Elements
Multiple Choice Questions (Type - I) | Q 33.(vi) | पृष्ठ १३८

संबंधित प्रश्‍न

How can you explain higher stability of BClas compared to TlCl3?


Suggest reasons why the B–F bond lengths in BF3 (130 pm) and `"BF"_4^(-)` (143 pm) differ.


What happens when BF3 is reacted with ammonia?


Which of the following statements are correct. Answer on the basis of Figure.

(i) The two birdged hydrogen atoms and the two boron atoms lie in one plane;

(ii) Out of six B – H bonds two bonds can be described in terms of 3 centre 2-electron bonds.

(iii) Out of six B – H bonds four B – H bonds can be described in terms of 3 centre 2 electron bonds;

(iv) The four-terminal B – H bonds are two centre-two electron regular bonds.


When BCl3 is treated with water, it hydrolyses and forms [B[OH]4] only whereas AlCl3 in acidified aqueous solution forms [Al(H2O)6]3+ ion. Explain what is the hybridisation of boron and aluminium in these species?


Aluminium dissolves in mineral acids and aqueous alkalies and thus shows amphoteric character. A piece of aluminium foil is treated with dilute hydrochloric acid or dilute sodium hydroxide solution in a test tube and on bringing a burning matchstick near the mouth of the test tube, a pop sound indicates the evolution of hydrogen gas. The same activity when performed with concentrated nitric acid, reaction doesn’t proceed. Explain the reason.


Match the species given in Column I with the properties mentioned in Column II.

Column I Column II
(i) \[\ce{BF^{-}4}\] (a) Oxidation state of central atom is +4
(ii) AICI3 (b) Strong oxidising agent
(iii) SnO (c) Lewis acid
(iv) PbO2 (d) Can be further oxidised
  (e) Tetrahedral shape

Describe the general trends in the following properties of the elements in Groups 13 and 14.

Atomic size


Describe the general trends in the following properties of the elements in Groups 13 and 14.

Ionisation enthalpy


Describe the general trends in the following properties of the elements in Groups 13 and 14.

Oxidation states


Share
Notifications

Englishहिंदीमराठी


      Forgot password?
Use app×