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The half life period of a radioactive element is 140 days. After 560 days, 1 g of element will be reduced to - Chemistry

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प्रश्न

The half life period of a radioactive element is 140 days. After 560 days, 1 g of element will be reduced to

पर्याय

  • `(1/2) "g"`

  • `(1/4) "g"`

  • `(1/8) "g"`

  • `(1/16) "g"`

MCQ

उत्तर

`(1/16) "g"`

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पाठ 7: Chemical Kinetics - Evaluation [पृष्ठ २२९]

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सामाचीर कलवी Chemistry - Volume 1 and 2 [English] Class 12 TN Board
पाठ 7 Chemical Kinetics
Evaluation | Q 23. | पृष्ठ २२९

संबंधित प्रश्‍न

The integrated rate equation for first order reaction is A → products


 A first order reaction takes 40 minutes for 30% decomposition. Calculate t1/2 for this reaction. (Given log 1.428 = 0.1548)


A first order reaction takes 30 minutes for 50% completion. Calculate the time required for 90% completion of this reaction.

(log 2 = 0.3010)


The experimental data for decomposition of N2O5

\[\ce{2N2O5 -> 4NO2 + O2}\] in gas phase at 318K are given below:

t/s 0 400 800 1200 1600 2000 2400 2800 3200
102 × [N2O5]/mol L−1 1.63 1.36 1.14 0.93 0.78 0.64 0.53 0.43 0.35
  1. Plot [N2O5] against t.
  2. Find the half-life period for the reaction.
  3. Draw a graph between log [N2O5] and t.
  4. What is the rate law?
  5. Calculate the rate constant.
  6. Calculate the half-life period from k and compare it with (ii).

Show that for a first order reaction half life is independent of initial concentration.


Which radioactive isotope would have the longer half-life 15O or 19O? (Given rate constants for 15O and 19O are 5.63 × 10–3 s–1 and k = 2.38 × 10–2 s–1 respectively.)


Observe the graph shown in figure and answer the following questions:


Write the relationship between k and t1/2 (half-life period)


Assertion (A): The half-life of a reaction is the time in which the concentration of the reactant is reduced to one-half of its initial concentration.

Reason (R): In first-order kinetics, when the concentration of reactant is doubled, its half-life is doubled.


Obtain a relation, `k_2/k_1 = ((t_(1/2))_2)/((t_(1/2))_1)`, where k1 and k2 are rate constants while (t1/2)and  (t1/2)are half-life periods of the first order reaction at temperatures T1 and Trespectively. Write the relation for activation energy.


Show that the half-life of zero order reaction is `t_(1/2) = ([A]_0)/(2k)`.


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