मराठी

What will be the work done on an ideal gas enclosed in a cylinder, when it is compressed by a constant external pressure, pext in a single step as shown in figure. Explain graphically. - Chemistry

Advertisements
Advertisements

प्रश्न

What will be the work done on an ideal gas enclosed in a cylinder, when it is compressed by a constant external pressure, pext in a single step as shown in figure. Explain graphically.

टीपा लिहा

उत्तर

Assumption: Cylinder is filled with one mole gas, and the piston is frictionless. Let the pressure of gas inside be p and the volume of gas be \[\ce{V_{I}}\].

Piston is moved towards the inside to make the external pressure \[\ce{(P_{ext})}\] equal to p. Now, let us assume that this change takes place in a single step, hence, \[\ce{V}\] is the final volume. The work done by the piston is depicted in the graph shown below by shading the area.

PextΔV = AV1 × (V1 – V2)

shaalaa.com
Thermodynamics Applications - Work
  या प्रश्नात किंवा उत्तरात काही त्रुटी आहे का?
पाठ 6: Thermodynamics - Multiple Choice Questions (Type - I) [पृष्ठ ७४]

APPEARS IN

एनसीईआरटी एक्झांप्लर Chemistry [English] Class 11
पाठ 6 Thermodynamics
Multiple Choice Questions (Type - I) | Q 45 | पृष्ठ ७४

संबंधित प्रश्‍न

A sample of 1.0 mol of a monoatomic ideal gas is taken through a cyclic process of expansion and compression as shown in figure 6.1. What will be the value of ∆H for the cycle as a whole?


Expansion of a gas in vacuum is called free expansion. Calculate the work done and the change in internal energy when 1 litre of ideal gas expands isothermally into vacuum until its total volume is 5 litre?


Represent the potential energy/enthalpy change in the following processes graphically.

(a) Throwing a stone from the ground to roof.

(b) \[\ce{1/2 H2(g) + 1/2 Cl2 (g) ⇌ HCl (g) Δ_rH^Θ = - 92.32 kJ mol^{-1}}\]

In which of the processes potential energy/enthalpy change is contributing factor to the spontaneity?


Match the following :

A B
(i) Adiabatic process (a) Heat
(ii) Isolated system (b) At constant volume
(iii) Isothermal change (c) First law of thermodynamics
(iv) Path function (d) No exchange of energy and matter
(v) State function (e) No transfer of heat
(vi) ΔU = q (f) Constant temperature
(vii) Law of conservation of energy (g) Internal energy
(viii) Reversible process (h) Pext = o
(ix) Free expansion (i) At constant pressure
(x) ΔH = q (j) Infinitely slow process which proceeds through a series of equilibrium states.
(xi) Intensive property (k) Entropy
(xii) Extensive property (l) Pressure
  (m) Specific heat

Match the following :

Column I Column II
(i) Entropy of vapourisation (a) decreases
(ii) K for spontaneous process (b) is always positive
(iii) Crystalline solid state (c) lowest entropy
(iv) ∆U in adiabatic expansion of ideal gas (d) `(∆H_(vap))/T_b`

1 mole of an ideal monoatomic gas initially at 1 atm and 300 K experiences a process by which pressure is doubled. The nature of the process is unspecified but 6. ΔU = 900 cal. The final volume will be ______ l.

[Given : R = 0.08 atm lit. I mol/K = 2 Cal/K/mol J]


1 mole of an ideal monoatomic gas initially at 1 atm and 300 K experiences a process by which pressure is doubled. The nature of the process is unspecified but 6. ΔU = 900 cal. The final volume will be ______ l.

[Given : R = 0.08 atm lit. I mol/K = 2 Cal/K/mol J]


Find the work done when 2 moles of hydrogen expand isothermally from 15 to 50 litres against a constant pressure of 1 atm at 25°C.


Five moles of an ideal gas at 1 bar and 298 K is expanded into the vacuum to double the volume. The work done is ______.


An ideal gas expands in volume from 1 × 10−3 to 1 × 10−2 m3 at 300 K against a constant pressure of 1 × 105 Nm−2. The work done is ______.


Share
Notifications

Englishहिंदीमराठी


      Forgot password?
Use app×