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What will be the work done on an ideal gas enclosed in a cylinder, when it is compressed by a constant external pressure, pext in a single step as shown in figure. Explain graphically. - Chemistry

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What will be the work done on an ideal gas enclosed in a cylinder, when it is compressed by a constant external pressure, pext in a single step as shown in figure. Explain graphically.

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Solution

Assumption: Cylinder is filled with one mole gas, and the piston is frictionless. Let the pressure of gas inside be p and the volume of gas be \[\ce{V_{I}}\].

Piston is moved towards the inside to make the external pressure \[\ce{(P_{ext})}\] equal to p. Now, let us assume that this change takes place in a single step, hence, \[\ce{V}\] is the final volume. The work done by the piston is depicted in the graph shown below by shading the area.

PextΔV = AV1 × (V1 – V2)

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Thermodynamics Applications - Work
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Chapter 6: Thermodynamics - Multiple Choice Questions (Type - I) [Page 74]

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NCERT Exemplar Chemistry [English] Class 11
Chapter 6 Thermodynamics
Multiple Choice Questions (Type - I) | Q 45 | Page 74

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