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Why Conductivity of an Electrolyte Solution Decreases with the Decrease in Concentration ? - Chemistry

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प्रश्न

Why conductivity of an electrolyte solution decreases with the decrease in concentration ?

उत्तर

The conductivity of an electrolyte solution is the conductance of ions present in a unit volume of the solution. The number of ions (responsible for carrying current) decreases when the solution is diluted or the concentration is decreased. As a result, the conductivity of an electrolyte solution decreases with the decrease in concentration.

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2014-2015 (March) Delhi Set 1

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संबंधित प्रश्‍न

Define "Molar conductivity".


Conductivity of 0.00241 M acetic acid is 7.896 × 10−5 S cm−1. Calculate its molar conductivity and if `∧_"m"^0` for acetic acid is 390.5 S cm2 mol−1, what is its dissociation constant?


10.0 grams of caustic soda when dissolved in 250 cm3 of water, the resultant gram molarity of solution is _______.

(A) 0.25 M

(B) 0.5 M

(C) 1.0 M

(D) 0.1 M


Define the following terms :

Limiting molar conductivity


The S.I. unit of cell constant for conductivity cell is __________.


Which of the statements about solutions of electrolytes is not correct?


Solutions of two electrolytes ‘A’ and ‘B’ are diluted. The Λm of ‘B’ increases 1.5 times while that of A increases 25 times. Which of the two is a strong electrolyte? Justify your answer. Graphically show the behavior of ‘A’ and ‘B’.


The molar conductance of \[\ce{NaCl, HCl}\] and \[\ce{CH3COONa}\] at infinite dilution are 126.45, 426.16 and 91.0 S cm2 mol−1 respectively. The molar conductance of \[\ce{CH3COOH}\] at infinite dilution is. Choose the right option for your answer.


Given below are two statements:

Statements I: The limiting molar conductivity of KCl (strong electrolyte) is higher compared to that of CH3COOH (weak electrolyte).

Statement II: Molar conductivity decreases with decrease in concentration of electrolyte.
In the light of the above statements, choose the most appropriate answer from the options given below:


Which of the following solutions will have the highest conductivity at 298 K? 


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