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Question
- A compound 'A' with a molecular formula of \[\ce{C2H4O2}\] reacts with a base to give salt and water. Identify 'A', state its nature and the name of the functional group it possesses. Write chemical equation for the reaction involved.
- When the above stated compound 'A' reacts with another compound 'B' having molecular formula \[\ce{C2H6O}\] in the presence of an acid, a sweet smelling compound is 'C' formed.
- Identify 'B' and 'C'.
- State the role of acid in this reaction.
- Write chemical equation for the reaction involved.
Solution
- Since acid and base react to form salt and water, compound A will naturally be acidic due to the presence of a carboxylic acid group.
Chemical equation for acid and base reaction:
\[\ce{Acid + Base-> Salt + Water}\]
\[\ce{H X + M OH -> MX + HOH}\]
\[\ce{CH3COOH(aq) + NaOH(aq) -> CH3COONa(aq) + H2O(l)}\]
Thus, Compound A is \[\ce{CH3COOH}\] it is acidic in nature containing a carboxyl functional group. - In a process known as Fischer esterification, carboxylic acids combine with alcohols to create esters. An acid catalyst is required, and alcohol serves as a reaction solvent.
- Compound B is Ethanol and C is Ethyl acetate.
- HCl act as catalyst.
- A sweet-smelling compound formed by reacting acetic acid with ethanol in the presence of hydrochloric acid is ethyl acetate.
\[\begin{array}{cc} \ce{CH3 - C - OH + HOC2H5 ->[H+] CH3 - C - OC2H5}\\ ||\phantom{..............................}||\phantom{..}\\ \phantom{...}\ce{O}\phantom{..........................}\ce{\underset{Ethyl acetate}{O}} \end{array}\]
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