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Aluminium crystallises in a cubic close-packed structure with a unit cell edge length of 353.6 pm. What is the radius of Al atom? How many unit cells are there in 1.00 cm3 of Al? - Chemistry

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Question

Aluminium crystallises in a cubic close-packed structure with a unit cell edge length of 353.6 pm. What is the radius of Al atom? How many unit cells are there in 1.00 cm3 of Al?

Sum

Solution

Using the formula (i),

r = 0.3535 a

∴ r = 0.3535 × 353.6 = 125 pm

Using the formula (ii),

Number of unit cells in volume (V) of metal = `"V"/"a"^3`

∴ Number of unit cells in 1.00 cm3 of Al = `1.00/(3.536 xx 10^-8)^3`

= 2.26 × 1022

  1. Radius of Al atom (r) is 125 pm.
  2. Number of unit cells in 1.00 cm3 of Al is 2.26 × 1022.
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