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Chemistry Model set 2 by shaalaa.com 2024-2025 HSC Science (General) 12th Standard Board Exam Question Paper Solution

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Chemistry [Model set 2 by shaalaa.com]
Marks: 70 Maharashtra State Board
HSC Science (General)
HSC Science (Electronics)
HSC Science (Computer Science)

Academic Year: 2024-2025
Date: March 2025
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General Instructions: The question paper is divided into four sections. 

  1. Section A: Q.No.1 contains Ten multiple-choice types of questions carrying One mark each. Q.No.2 contains Eight very short answer type of questions carrying One mark each.
  2. Section B: Q.No.3 to Q.No.14 are Twelve short answer type questions carrying Two marks each. (Attempt any Eight).
  3. Section C: Q.No.15 to Q.No.26 are Twelve short answer type questions carrying Three marks each. (Attempt any Eight).
  4.  Section D: Q.No.27 to Q.No.31 are Five Long answer-type questions carrying Four marks each. (Attempt any Three).
  5. Use of Log table is allowed. Use of calculator is not allowed.
  6. Figures to the right indicate full marks.
  7.  For each multiple-choice type question, it is mandatory to write the correct answer along with its alphabet. e.g., (a) .............. /(b) ............... /(c) ............... /(d) ................ ,etc. No mark(s) shall be given if ONLY the correct answer or the alphabet of the correct answer is written.
    Only the first attempt will be considered for evaluation. 

SECTION - A
[10]1 | Select and write the correct answer for the following multiple-choice type of questions:
[1]1.i

Choose the most correct option.

Components of Nichrome alloy are _______.

Ni, Cr, Fe

Ni, Cr, Fe, C

Ni, Cr

Cu, Fe

Concept: undefined - undefined
Chapter: [0.08] Transition and Inner Transition Elements
[1]1.ii

Choose the most correct option.

Pressure cooker reduces cooking time for food because _______.

boiling point of water involved in cooking is increased

heat is more evenly distributed in the cooking space

the higher pressure inside the cooker crushes the food material 

cooking involves chemical changes helped by a rise temperature

Concept: undefined - undefined
Chapter: [0.02] Solutions
[1]1.iii

Choose the most correct option.

A living cell contains a solution which is isotonic with 0.3 M sugar solution. What osmotic pressure develops when the cell is placed in 0.1 M KCl solution at body temperature?

5.08 atm

2.54 atm

4.92 atm

2.46 atm

Concept: undefined - undefined
Chapter: [0.02] Solutions [0.02] Solutions and Colligative Properties
[1]1.iv

Choose the most correct option.

Which of the following is not correct?

Gibbs energy is an extensive property

Electrode potential or cell potential is an intensive property

Electrical work = – ΔG

If half-reaction is multiplied by a numerical factor, the corresponding E° value is also multiplied by the same factor.

Concept: undefined - undefined
Chapter: [0.05] Electrochemistry
[1]1.v

Choose the correct option from the given alternatives.

The number of carbon atoms present in the ring of ɛ-caprolactam is ______.

Five

Two

Seven

Six

Concept: undefined - undefined
Chapter: [0.15] Introduction to Polymer Chemistry
[1]1.vi

In which reaction mechanism carbocation is formed?

SN1

SN2

Both SN1 and SN2

None of them

Concept: undefined - undefined
Chapter: [10.01] Haloalkanes
[1]1.vii

Select appropriate answers for the following.

Which of the following has highest electron gain enthalpy?

Fluorine

Chlorine

Bromine

Iodine

Concept: undefined - undefined
Chapter: [0.07] Elements of Groups 16, 17 and 18
[1]1.viii

Isobutylamine is an example of ______.

2° amine

3° amine

1° amine

quaternary ammonium salt

Concept: undefined - undefined
Chapter: [0.13] Amines [13.01] Amines
[1]1.ix

The molecule of glucose is also called ______.

Glucopyranose

Pyranose

Rabinose

None of them

Concept: undefined - undefined
Chapter: [0.14] Biomolecules
[1]1.x

Choose the most correct answer :

For pH > 7 the hydronium ion concentration would be _________.

10-7M

< 10-7M

> 10-7M

≥ 10-7M

Concept: undefined - undefined
Chapter: [0.03] Ionic Equilibria
[8]2 | Answer the following questions:
[1]2.i

Answer the following in one sentence.

Write examples of addition polymers and condensation polymers.

Concept: undefined - undefined
Chapter: [0.15] Introduction to Polymer Chemistry
[1]2.ii

Why tryptophan is an essential amino acid?

Concept: undefined - undefined
Chapter: [14.02] Proteins
[1]2.iii

Answer in one sentence.

Which amide does produce ethanamine by Hofmann bromamide degradation reaction?

Concept: undefined - undefined
Chapter: [0.13] Amines [13.01] Amines
[1]2.iv

Answer in one sentence/ word.

Write the name of the electrophile used in Kolbe’s Reaction.

Concept: undefined - undefined
Chapter: [0.11] Alcohols, Phenols and Ethers
[1]2.v

Answer the following in one or two sentences.

What is the relationship between coefficients of reactants in a balanced equation for an overall reaction and exponents in the rate law? In what case the coefficients are the exponents?

Concept: undefined - undefined
Chapter: [0.06] Chemical Kinetics
[1]2.vi

Answer in one sentence.

Write the reaction of p-toluenesulphonyl chloride with diethylamine.

Concept: undefined - undefined
Chapter: [0.13] Amines
[1]2.vii

Answer the following in brief.

How instantaneous rate of reaction is determined?

Concept: undefined - undefined
Chapter: [0.06] Chemical Kinetics
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[1]2.viii

Name a compound where Frenkel defect is found.

Concept: undefined - undefined
Chapter: [0.01] Solid State
SECTION - B
[2]3 | Attempt any EIGHT of the following questions:

Why alkyl halides though polar are immiscible with water?

Concept: undefined - undefined
Chapter: [10.01] Haloalkanes
[2]4

Answer in brief.

What are ionization isomers ? Give an example.

Concept: undefined - undefined
Chapter: [0.09] Coordination Compounds
[2]5

What is Henry's law?

Concept: undefined - undefined
Chapter: [0.02] Solutions
[2]6

Answer the following.

What are isotonic and hypertonic solutions?

Concept: undefined - undefined
Chapter: [0.02] Solutions [0.02] Solutions and Colligative Properties
[2]7

Give scientific reasons:

α-Amino acids have high melting points compared to the corresponding amines or carboxylic acids of comparable molecular mass.

Concept: undefined - undefined
Chapter: [0.14] Biomolecules
[2]8

Write IUPAC names of following compounds.

Concept: undefined - undefined
Chapter: [0.1] Halogen Derivatives

Write IUPAC names of following compounds.

Concept: undefined - undefined
Chapter: [0.1] Halogen Derivatives
[2]9

Answer the following in brief.

Construct a galvanic cell from the electrodes Co3+ | Co and Mn2+/Mn. `"E"_"Co"^circ` = 1.82 V, `"E"_"Mn"^circ` = –1.18 V. Calculate `"E"_"cell"^circ`

Concept: undefined - undefined
Chapter: [0.05] Electrochemistry
[2]10

Answer the following in one or two sentences.

Write Nernst equation. What part of it represents the correction factor for nonstandard state conditions?

Concept: undefined - undefined
Chapter: [0.05] Electrochemistry
[2]11

Give the reactions involved in the Etard's reaction.

Concept: undefined - undefined
Chapter: [0.12] Aldehydes, Ketones and Carboxylic Acids [12.01] Aldehydes and Ketones
[2]12

Answer the following in brief :

What are acids and bases according to Arrhenius theory?

Concept: undefined - undefined
Chapter: [0.03] Ionic Equilibria
[2]13

Give reason:

Alkyl halides are generally not prepared by free radical halogenation of alkanes.

Concept: undefined - undefined
Chapter: [0.1] Halogen Derivatives
[2]14

Answer the following

Give the full form (long form) of the name for following instrument.

XRD

Concept: undefined - undefined
Chapter: [0.16] Green Chemistry and Nanochemistry

Answer the following

Give the full form (long form) of the name for the following instrument.

TEM

Concept: undefined - undefined
Chapter: [0.16] Green Chemistry and Nanochemistry
SECTION - C
[3]15 | Attempt any EIGHT of the following questions:

Complete the following reaction sequence by writing the structural formulae of the organic compound 'A', 'B' and 'C'.

\[\ce{2-Bromobutane->[Alc.KOH]A->[][Br2]B->[][NaNH2]C}\]

Concept: undefined - undefined
Chapter: [0.1] Halogen Derivatives
[3]16

The vapour pressure of water at 20°C is 17 mm Hg. What is the vapour pressure of solution containing 2.8 g urea in 50 g of water?

Concept: undefined - undefined
Chapter: [0.02] Solutions
[3]17

What are pseudo-first-order reactions?

Concept: undefined - undefined
Chapter: [0.06] Chemical Kinetics

Answer the following in brief.

Give one example and explain why it is pseudo-first-order.

Concept: undefined - undefined
Chapter: [0.06] Chemical Kinetics
[3]18

Attempt the following:

Write preparation, properties and uses of Teflon.

Concept: undefined - undefined
Chapter: [0.15] Introduction to Polymer Chemistry [0.15] Polymers
[3]19

Answer the following question.

Give valence bond description for the bonding in the complex [VCl4]-. Draw box diagrams for the free metal ion. Which hybrid orbitals are used by the metal? State the number of unpaired electrons.

Concept: undefined - undefined
Chapter: [0.09] Coordination Compounds
[3]20

Distinguish between ethylamine, diethylamine, and triethylamine by using Hinsberg’s reagent?

Concept: undefined - undefined
Chapter: [0.13] Amines
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[3]21
[1]21.i

Calculate the standard enthalpy of:

\[\ce{N2H_{4(g)} + H_{2(g)} -> 2NH_{3(g)}}\]

If ΔH0(N – H) = 389 kJ mol–1, ΔH0(H – H) = 435 kJ mol–1, ΔH0(N – N) = 159 kJ mol–1.

Concept: undefined - undefined
Chapter: [0.04] Chemical Thermodynamics
[2]21.ii

The enthalpy change of the following reaction:

\[\ce{CH_{4(g)} + Cl_{2(g)} -> CH3Cl_{(g)} + HCl_{(g)}ΔH^0 = –104 kJ}\]

Calculate C – Cl bond enthalpy. The bond enthalpies are:

Bond C − H Cl − Cl H − Cl
∆H°/kJ mol−1 414 243 431
Concept: undefined - undefined
Chapter: [0.04] Chemical Thermodynamics
[3]22

Write a note on Stephen reaction.

Concept: undefined - undefined
Chapter: [0.12] Aldehydes, Ketones and Carboxylic Acids
[3]23
[1]23.i

Write reaction showing aldol condensation of cyclohexanone.

Concept: undefined - undefined
Chapter: [0.12] Aldehydes, Ketones and Carboxylic Acids
[1]23.ii

How acetone is converted into propane.

Concept: undefined - undefined
Chapter: [0.12] Aldehydes, Ketones and Carboxylic Acids
[1]23.iii

How propanal is converted into propane.

Concept: undefined - undefined
Chapter: [0.12] Aldehydes, Ketones and Carboxylic Acids
[3]24

Aluminium crystallises in a cubic close-packed structure with a unit cell edge length of 353.6 pm. What is the radius of Al atom? How many unit cells are there in 1.00 cm3 of Al?

Concept: undefined - undefined
Chapter: [0.01] Solid State
[3]25

Answer the following

What is meant by diamagnetic and paramagnetic? Give one example of diamagnetic and paramagnetic transition metal and lanthanoid metal.

Concept: undefined - undefined
Chapter: [0.08] Transition and Inner Transition Elements
[3]26

Answer the following question.

State Hess’s law of constant heat summation. Illustrate with an example. State its applications.

Concept: undefined - undefined
Chapter: [0.04] Chemical Thermodynamics
SECTION - D
[4]27 | Attempt any THREE of the following questions:

Give the properties of Lanthanoids.

Concept: undefined - undefined
Chapter: [0.08] Transition and Inner Transition Elements
[4]28
[2]28.i

Answer the following.

Give two reactions showing the oxidising property of concentrated H2SO4.

Concept: undefined - undefined
Chapter: [0.07] Elements of Groups 16, 17 and 18
[1]28.ii

Draw the structures of the HClO3.

Concept: undefined - undefined
Chapter: [7.03] Group 17 Elements
[1]28.iii

Write the structure of HClO4.

Concept: undefined - undefined
Chapter: [0.07] Elements of Groups 16, 17 and 18
[4]29

Describe the manufacturing of H2SO4 by the contact process.

Concept: undefined - undefined
Chapter: [0.07] Elements of Groups 16, 17 and 18
[4]30

The density of iridium is 22.4 g/cm3. The unit cell of iridium is fcc. Calculate the radius of iridium atom. Molar mass of iridium is 192.2 g/mol.

Concept: undefined - undefined
Chapter: [0.01] Solid State
[4]31

Explain optical isomerism in 2-chlorobutane.

Concept: undefined - undefined
Chapter: [0.1] Halogen Derivatives

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