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Copper sulphate solution cannot be stored in a zinc pot. Why? - Chemistry (Theory)

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Question

Copper sulphate solution cannot be stored in a zinc pot. Why?

One Line Answer

Solution

No, zinc is placed above copper in electrochemical series.

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Galvanic Cells, Mechanism of Current Production in a Galvanic Cell; - Electrochemical Series
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2024-2025 (April) Specimen Paper

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The following electrochemical cell is set up at 298 K:

`"Zn"//"Zn"^(2+)("aq")(1"M")////"Cu"^(2+)("aq")(1"M")//"Cu"`

Given`-> "E"_("Zn"^(2+)//"2n")^0 = -0.761"V", "E"_("Cu"^(2+)//"Cu")^0 = +0.339"V"`

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The following electrochemical cell is set up at 298 K: 

`"Zn"//"Zn"^(2+)("aq")(1"M")////"Cu"^(2+)("aq")(1"M")//"Cu"`

Given`-> "E"_("Zn"^(2+)//"2n")^0 = -0.761"V", "E"_("Cu"^(2+)//"Cu")^0 = +0.339"V"`

Calculate the emf and free energy change at 298 K.


What is an electrochemical series? How is it useful in predicting whether a metal can liberate hydrogen from acid or not?


Study the diagram given below that represents Cu-Ag electrochemical cell and answer the questions that follow.

Given \[\ce{E^0_{(Cu^{2+}/Cu)}}\] = 0.337V; \[\ce{E^0_{(Ag^+/Ag)}}\] = 0.799V

  1. Write the cell reaction for the above cell.
  2. Calculate the standard emf of the cell.
  3. If the concentration of [Cu2+] is 0.1 M and Ecell is 0.422 V, at 25°C, calculate the concentration of [Ag+].
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