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Question
Derive an expression for finding out the specific heat capacity of a body (solid) from the readings of an experiment given below:
(i) Mass of empty calorimeter (with stirrer) = m1 gm
(ii) Mass of the metal piece = M gm
(iii) Mass of colorimeter and water = m2 gm
(iv) Initial temperature and water = t1°C
(v) Temperature of hot solid (metal piece) = t2 °C
(vi) Final temperature of the mixture = t°C
(vii) Specific heat of calorimeter = 0.4 J gm / °C
Solution
Lets J gm / °C be the specific heat of the solid
(i) Fall in temperature of hot solid = (t2 - t) °C
(ii) Rise in the temperature of calorimeter as well as water = (t - t2) °C
(iii) Heat taken up by calorimeter = m1 × 0.4 × (t - t1) °C
(iv) Heat taken up by water = (m2 - m1) × 4.2 × (t - t1)°C
(v) Heat given out by hot soild = M × s × (t2 - t)°C
Now, heat given out by hot solid = Heat taken up by calorimeter + Heat taken up by water
or Ms (t2 - t) = m1 × 0.4 (t - t1) + (m2 - m1) × (4.2 × (t - t1))
From this heat equation, 's' can b e calculated where all other values are known.
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