Advertisements
Advertisements
Question
`E_(cell)^Θ` = 1.1V for Daniel cell. Which of the following expressions are correct description of state of equilibrium in this cell?
(i) 1.1 = `K_c`
(ii) `(2.303RT)/(2F) logK_c` = 1.1
(iii) `log K_c = 2.2/0.059`
(iv) `log K_c` = 1.1
Solution
(ii) `(2.303RT)/(2F) logK_c` = 1.1
(iii) `log K_c = 2.2/0.059`
Explanation:
`E_(cell)^Θ = (2.303RT)/(2F) logK_c`
or `E_(cell)^Θ = 0.059/2 log K_c` or 1.1 = `0.059/2 loc K_c`
or `log K_C = 2.2/0.059`
APPEARS IN
RELATED QUESTIONS
Define cathode
Reduction potential of two metals M1 and M2 are \[\ce{E^0_{{M_1^{2+}|M_1}}}\] = −2.3 V and \[\ce{E^0_{{M_2^{2+}|M_2}}}\] = 0.2 V. Predict which one is better for coating the surface of iron.
Given: \[\ce{E^0_{{Fe^{2+}|Fe}}}\] = −0.44 V
`E_(cell)^Θ` for some half cell reactions are given below. On the basis of these mark the correct answer.
(a) \[\ce{H^{+} (aq) + e^{-} -> 1/2 H_2 (g); E^Θ_{cell} = 0.00V}\]
(b) \[\ce{2H2O (1) -> O2 (g) + 4H^{+} (aq) + 4e^{-}; E^Θ_{cell} = 1.23V}\]
(c) \[\ce{2SO^{2-}_{4} (aq) -> S2O^{2-}_{8} (aq) + 2e^{-}; E^Θ_{cell} = 1.96V}\]
(i) In dilute sulphuric acid solution, hydrogen will be reduced at cathode.
(ii) In concentrated sulphuric acid solution, water will be oxidised at anode.
(iii) In dilute sulphuric acid solution, water will be oxidised at anode.
(iv) In dilute sulphuric acid solution, \[\ce{SO4^{2-}}\] ion will be oxidised to tetrathionate ion at anode.
Can absolute electrode potential of an electrode be measured?
A galvanic cell has electrical potential of 1.1V. If an opposing potential of 1.1V is applied to this cell, what will happen to the cell reaction and current flowing through the cell?
Consider a cell given below:
\[\ce{Cu | Cu^{2+} || Cl^{-} | Cl_{2},Pt}\]
Write the reactions that occur at anode and cathode
Standard reduction electrode potentials of three metals A, B and C are respectively + 0.5 V, – 3.0 V. and – 1.2 V. The reducing powers of there metal is.
In a Daniel cell, ______.
The number of moles of electrons passed when the current of 2 A is passed through a solution of electrolyte for 20 minutes is ______.
The cell constant of a conductivity cell is 0.146 cm-1. What is the conductivity of 0.01 M solution of an electrolyte at 298 K, if the resistance of the cell is 1000 ohm?
