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Can absolute electrode potential of an electrode be measured? - Chemistry

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Question

Can absolute electrode potential of an electrode be measured?

Short Note

Solution

No. It cannot be measured. We can only measure the difference in electrode potential between the two half-cells. We can also measure electrode potential difference concerning a standard electrode.

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Chapter 3: Electrochemistry - Exercises [Page 38]

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NCERT Exemplar Chemistry [English] Class 12
Chapter 3 Electrochemistry
Exercises | Q III. 28. | Page 38

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  2. What will happen if the salt bridge is removed?  (1)
  3. When does electrochemical cell behaves like an electrolytic cell?  (1)
  4. (i) What will happen to the concentration of Zn2+ and Ag+ when Ecell = 0.   (1)
    (ii) Why does conductivity of a solution decreases with dilution?  (1)
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    The molar conductivity of a 1.5 M solution of an electrolyte is found to be 138.9 S cm2mol-1. Calculate the conductivity of this solution.  (2)

Can we construct an electrochemical cell with two half-cells composed of ZnSO4 solution and zinc electrodes? Explain your answer.


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