Advertisements
Advertisements
Question
How are the following compounds prepared?
benzaldehyde from benzoyl chloride
Solution
Benzaldehyde from benzoyl chloride
Rosenmund Reduction
APPEARS IN
RELATED QUESTIONS
Acetaldehyde, when treated with which among the following reagents does NOT undergo addition reaction?
(A) Ammonia
(B) Hydroxylamine
(C) Ammoniacal silver nitrate
(D) Semicarbazide
Draw the structure of the semicarbazone of ethanal.
Predict the product of the following reaction:
Predict the product of the following reaction:
\[\begin{array}{cc}
\phantom{..............}\ce{O}\\
\phantom{..............}||\\
\ce{R - CH = CH - CHO + NH2 - C - NH - NH2 ->[H+]}\end{array}\]
What is meant by the following term? Give an example of the reaction in the following case.
Acetal
What is meant by the following term? Give an example of the reaction in the following case.
Semicarbazone
What is meant by the following term? Give an example of the reaction in the following case.
Oxime
What is meant by the following term? Give an example of the reaction in the following case.
2, 4-DNP-derivative
Give plausible explanation for the following:
Cyclohexanone forms cyanohydrin in good yield but 2, 2, 6 trimethylcyclohexanone does not.
Complete the synthesis by giving missing starting material, reagent or product.
\[\ce{C6H5CHO ->[H2NCONHNH2]}\]
Write balanced chemical equations for action of ammonia on - acetaldehyde
Write the main product formed when propanal reacts with the following reagents:
2 moles of 3 CH OH in presence of dry HCl
How will you convert benzoic acid to m-bromobenzoic acid?
Benzaldehyde can be obtained from benzal chloride. Write reactions for obtaining benzalchloride and then benzaldehyde from it.
Reaction of aqueous sodium hydroxide on chlorobenzene gives which of the following products?
Which one of the following gives only one monochloro derivative?
Which of the following has the most acidic hydrogen?
Paraldehyde is formed as a result of polymerisation:-
The following questions are case-based questions. Read the passage carefully and answer the questions that follow:
| The carbon-oxygen double bond is polarised in aldehydes and ketones due to higher electronegativity of oxygen relative to carbon. Therefore, they undergo nucleophilic addition reactions with a number of nucleophiles such as HCN, NaHSO3, alcohols, ammonia derivatives and Grignard reagents. Aldehydes are easily oxidised by mild oxidising agents as compared to ketones. The carbonyl group of carboxylic acid does not give reactions of aldehydes and ketones. Carboxylic acids are considerably more acidic than alcohols and most of simple phenols. |
Answer the following:
(a) Write the name of the product when an aldehyde reacts with excess alcohol in the presence of dry HCl. (1)
(b) Why carboxylic acid is a stronger acid than phenol? (1)
(c) (i) Arrange the following compounds in increasing order of their reactivity towards CH3MgBr: (1)
CH3CHO, \[\begin{array}{cc}
\ce{(CH3)3C-C-CH3}\\
\phantom{....}||\\
\phantom{....}\ce{O}
\end{array}\], \[\begin{array}{cc}
\ce{CH3-C-CH3}\\
||\\
\ce{O}
\end{array}\]
(ii) Write a chemical test to distinguish between propanal and propanone. (1)
OR
(c) Write the main product in the following: (2)
| (i) |  |
| (ii) |  |
Aldehydes and ketones react with hydroxylamine to form ______.
Out of p-tolualdehyde and p-nitrobenzaldehyde, which one is more reactive towards nucleophilic addition reactions, why?
Draw structures of the given derivatives.
The ethylene ketal of hexan-3-one
Draw structure of the following derivative.
The ethylene ketal of hexane-3-one
Draw structures of the following derivative.
The ethylene ketal of hexan-3-one
Draw structure of the following derivative.
The ethylene ketal of hexan-3-one
Draw structure of the following derivative.
The ethylene ketal of hexan-3-one
Draw structure of the following derivative.
The ethylene ketal of hexan-3-one
Give an example of the reaction in the following case.
Oxime
