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Karnataka Board PUCPUC Science 2nd PUC Class 12

How would you account for the following: Cobalt (II) is stable in aqueous solutions, but in the presence of complexing reagents, it is easily oxidised. - Chemistry

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Question

How would you account for the following:

Cobalt (II) is stable in aqueous solutions, but in the presence of complexing reagents, it is easily oxidised.

Explain

Solution

In the presence of complexing reagents, the crystal field stabilization energy is greater than the third ionization enthalpy of cobalt. Thus, Co (II) is easily oxidized to Co (III).

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Chapter 8: The d-block and f-block Elements - Exercises [Page 235]

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NCERT Chemistry [English] Class 12
Chapter 8 The d-block and f-block Elements
Exercises | Q 21.2 | Page 235

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