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Tamil Nadu Board of Secondary EducationHSC Science Class 12

Identify A, B, C and D. ethanoic acid→SOClX2A→Pd/BaSOX4B→NaOHC→ΔD - Chemistry

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Question

Identify A, B, C and D.

\[\ce{ethanoic acid ->[SOCl2] A ->[Pd/BaSO4] B ->[NaOH] C ->[][\Delta] D}\]

Answer in Brief

Solution

\[\begin{array}{cc}
\ce{\underset{(Ethanoic acid)}{CH3COOH} ->[SOCl2] \underset{\underset{(A)}{(Acetyl chloride)}}{CH3COCl} ->[Pd/BaSO4][H2] \underset{\underset{(B)}{(Acetaldehyde)}}{CH3CHO} + HCl ->[NaOH] \ce{CH3 - CH - CH2 - CHO} ->[-H2O][\Delta] \underset{\underset{(D)}{(Crotonaldehyde)}}{CH3 - CH = CH - CHO}}\\
\phantom{........................}|\\
\phantom{...........................}\ce{\underset{\underset{(C)}{(Aldol 3-hydroxy butanal)}}{OH}}
\end{array}\]

A CH3Cl Acetyl chloride
B CH3CHO Acetaldehyde
C \[\begin{array}{cc}
\ce{CH3 - CH - CH2 - CHO}\\
|\phantom{..........}\\
\ce{OH}\phantom{.......}
\end{array}\]
3-hydroxy butanal
D CH3 – CH = CH – CHO Crotonaldehyde
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Chemical Properties of Aldehydes and Ketones
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Chapter 12: Carbonyl Compounds and Carboxylic Acids - Evaluation [Page 193]

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Samacheer Kalvi Chemistry - Volume 1 and 2 [English] Class 12 TN Board
Chapter 12 Carbonyl Compounds and Carboxylic Acids
Evaluation | Q 5. | Page 193
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