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Tamil Nadu Board of Secondary EducationHSC Science Class 11

The reaction between aluminium and ferric oxide can generate temperatures up to 3273 K and is used in welding metals. - Chemistry

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Question

The reaction between aluminium and ferric oxide can generate temperatures up to 3273 K and is used in welding metals.
(Atomic mass of Al = 27 u Atomic mass of O = 16 u)
\[\ce{2Al + Fe2O3 -> Al2O3 + 2Fe}\]; If, in this process, 324 g of aluminium is allowed to react with 1.12 kg of ferric oxide.

  1. Calculate the mass of Al2O3 formed.
  2. How much of the excess reagent is left at the end of the reaction?
Numerical

Solution

Given \[\ce{2Al + Fe2O3 -> Al2O3 + 2Fe}\]

  Reactants Products
Al Fe2O3 Al2O3 Fe
Amount of reactant allowed to react 324 g 1.12 kg - -
Number of moles allowed to react `324/27` = 12 mol `(1.12 xx 10^3)/160` = 7 mol - -
Stoichiometric Co-efficient 2 1 1 2
Number of moles consumed during the reaction 12 mol 6 mol - -
Number of moles of reactant unreacted and number of moles of product formed - 1 mol 6 mol 12 mol

Molar mass of Al2O3 formed = 6 mol × 102 g mol–1 ........[Al2O3 = (2 × 27) + (3 × 16) = 54 + 48 = 102]

= 612 g

Excess reagent = Fe2O3.
Amount of excess reagent left at the end of the reaction = 1 mol × 160 g mol–1

= 160 g ........[Fe2O3 = (2 × 56) + (3 × 16) = 112 + 48 = 160 g]

= 160 g

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Atomic and Molecular Masses
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Chapter 1: Basic Concepts of Chemistry and Chemical Calculations - Evaluation [Page 34]

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Samacheer Kalvi Chemistry - Volume 1 and 2 [English] Class 11 TN Board
Chapter 1 Basic Concepts of Chemistry and Chemical Calculations
Evaluation | Q II. 13) | Page 34
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