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Question
What are electrophiles and nucleophiles? Explain with examples.
Solution
An electrophile is a reagent that takes away an electron pair. In other words, an electron-seeking reagent is called an electrophile (E+). Electrophiles are electron-deficient and can receive an electron pair.
Carbocations (
A nulceophile is a reagent that brings an electron pair. In other words, a nucleus-seeking reagent is called a nulceophile (Nu:).
For example: OH–, NC–, carbanions (R3C–), etc.
Neutral molecules such as H2Ö and ammonia also act as nulceophiles because of the presence of a lone pair.
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RELATED QUESTIONS
Identify the reagents shown in bold in the following equation as nucleophiles or electrophiles:
The reaction:
Identify the reagents shown in bold in the following equation as nucleophiles or electrophiles:
Identify the reagents shown in bold in the following equation as nucleophiles or electrophiles:
Electrophiles are electron seeking species. Which of the following groups contain only electrophiles?
(i)
(ii)
(iii)
(iv)
Nucleophile is a species that should have:
(i) A pair of electrons to donate
(ii) Positive charge
(iii) Negative charge
(iv) Electron-deficient species
Why does SO3 act as an electrophile?
Match the terms mentioned in Column I with the terms in Column II.
Column I | Column II |
(i) Carbocation | (a) Cyclohexane and 1-hexene |
(ii) Nucleophile of | (b) Conjugation of electrons of C – H σ bond with empty p-orbital present at adjacent positively charged carbon. |
(iii) Hyperconjugation | (c) sp2 hybridised carbon with empty p-orbital |
(iv) Isomers | (d) Ethyne |
(v) sp hybridisation | (e) Species that can receive a pair of electrons |
(vi) Electrophile | (f) Species that can supply a pair of electrons |