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Tamil Nadu Board of Secondary EducationHSC Science Class 12

What happens when Nitrobenzene undergoes electrolytic reduction in a strongly acidic medium? - Chemistry

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Question

What happens when Nitrobenzene undergoes electrolytic reduction in a strongly acidic medium?

Short Note

Solution

Electrolytic reduction of nitrobenzene in weakly acidic medium gives aniline but in strongly acidic medium, it gives p-amino phenol obviously through the acid catalysed rearrangement of the initially formed phenyl hydroxylamine.

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Nitro Compounds
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Chapter 13: Organic Nitrogen Compounds - Evaluation [Page 233]

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Samacheer Kalvi Chemistry - Volume 1 and 2 [English] Class 12 TN Board
Chapter 13 Organic Nitrogen Compounds
Evaluation | Q 3. ii. | Page 233
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