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Which will undergo faster nucleophilic addition reaction? Acetaldehyde or Propanone - Chemistry

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Question

Which will undergo faster nucleophilic addition reaction?

Acetaldehyde or Propanone

Short Answer

Solution

Aldehydes are generally more reactive than ketones in nucleophilic addition reactions due to steric hindrance. As the electron density at the carbonyl carbon increases, the +I effect increases, which decreases the chances of attack by a nucleophile. Thus, acetaldehyde is more reactive than propanone.

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2021-2022 (April) Term 2 - Outside Delhi Set 1
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