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प्रश्न
Account for the following:
Reduction of nitrobenzene using Fe and HCl is preferred over Sn and HCl.
उत्तर
Reduction with iron scrap and hydrochloric acid is preferred because FeCl2 formed gets hydrolysed to release hydrochloric acid during the reaction. Thus, only a small amount of hydrochloric acid is required to initiate the reaction.
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संबंधित प्रश्न
Write the product in the following reaction
Write the product in the following reaction:
Write the chemical equations to illustrate the following name reactions : Rosenmund reduction
How will you prepare the given compound from benzene? You may use any inorganic reagent and any organic reagent having not more than one carbon atom.
p-Nitrobenzaldehyde
Aldehydes are produced on reduction of the following by DIBAL-H:
Match the common names given in Column I with the IUPAC names given in Column II.
| Column I (Common names) |
Column II (IUPAC names) |
||
| (i) | Cinnamaldehyde | (a) | Pentanal |
| (ii) | Acetophenone | (b) | Prop-2-enal |
| (iii) | Valeraldehyde | (c) | 4-Methylpent-3-en-2-one |
| (iv) | Acrolein | (d) | 3-Phenylprop-2-enal |
| (v) | Mesityl oxide | (e) | 1-Phenylethanone |
Aldehydes are the first oxidation products of ______.
Assertion (A): Strong oxidising agents oxidise toluene and its derivatives to benzoic acids.
Reason (R): It is possible to stop the oxidation of toluene at the aldehyde stage with suitable reagents.
Select the most appropriate answer from the options given below:
An organic compound with molecular formula \[\ce{C7H7NO2}\] exists in three isomeric forms, the isomer ‘A’ has the highest melting point of the three. ‘A’ on reduction gives compound ‘B’ with molecular formula \[\ce{C7H9N}\]. ‘B’ on treatment with \[\ce{NaNO2/HCl}\] at 0-5° C to form compound ‘C’. On treating C with \[\ce{H3PO2}\], it gets converted to D with formula \[\ce{C7H8}\], which on further reaction with \[\ce{CrO2Cl2}\] followed by hydrolysis forms ‘E’ \[\ce{C7H6O}\]. Write the structure of compounds A to E. Write the chemical equations involved.
Write the name of the reaction, structure and IUPAC name of the product formed when:
CH3CH2CN reacts with stannous chloride in the presence of hydrochloric acid, followed by hydrolysis.
