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प्रश्न
Assertion: Aldehydes and ketones, both react with Tollen’s reagent to form silver mirror.
Reason: Both, aldehydes and ketones contain a carbonyl group.
विकल्प
Assertion and reason both are correct and reason is correct explanation of assertion.
Assertion and reason both are wrong statements.
Assertion is correct statement but reason is wrong statement.
Assertion is wrong statement but reason is correct statement.
Assertion and reason both are correct statements but reasson is not correct explanation of assertion.
उत्तर
Assertion is wrong statement but reason is correct statement.
Explanation:
The silver mirror test can be used to determine Tollen's. \[\ce{[Ag(NH2)2]+ OH-}\]. Only aldehydes, not ketones, react with Tollen's reagent to create silver.
A silver mirror test is not given with this affirmative test.
The carbonyl group is present in both aldehyde and ketone.
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संबंधित प्रश्न
Name the reagents used in the following reactions:
How will you prepare the given compound from benzene? You may use any inorganic reagent and any organic reagent having not more than one carbon atom.
Phenylacetic acid
Which is the most suitable reagent for the following conversion?
\[\begin{array}{cc}
\phantom{....................}\ce{O}\phantom{.....................................}\ce{O}\phantom{.}\\
\phantom{....................}||\phantom{......................................}||\phantom{.}\\
\phantom{}\ce{CH3 - CH = CH - CH2 - C - CH3 -> CH3 - CH = CH - CH2 - C - OH}\phantom{.}
\end{array}\]
Through which of the following reactions number of carbon atoms can be increased in the chain?
(i) Grignard reaction
(ii) Cannizaro’s reaction
(iii) Aldol condensation
(iv) HVZ reaction
Substitution of one alkyl group by replacing hydrogen of primary amines
Match List - I with List - II.
| List - I | List - II | ||
| (a) |  \[\ce{->[CO,HCl][Anhyd. AlCl3/CuCl]}\] |
(i) | Hell-Volhard-Zelinsky reaction |
| (b) |
\[\begin{array}{cc}
\ce{O}\phantom{.................}\\ ||\phantom{.................}\\ \ce{R - C - CH3 + NaOX ->} \end{array}\] |
(ii) | Gattermann-Koch reaction |
| (c) | \[\ce{R - CH2 - OH + R'COOH ->[Conc. H2SO4]}\] | (iii) | Haloform reaction |
| (d) | \[\ce{R - CH2COOH ->[(i) X2/Red P][(ii) H2O]}\] | (iv) | Esterification |
Choose the correct answer from the options given below.
The end product Y in the sequence of reaction:
\[\ce{RX ->[CN^-] X ->[NaOH] Y}\] is:
Alkaline hydrolysis of C4H8Cl2 gives a compound (A) which on heating with NaOH and I2 produces a yellow precipitate of CHI3. The compound (A) should be ______.
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Fill in the blanks by choosing the appropriate words from those given in the brackets:
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The primary alcohols are easily oxidised first into ______ and then into ______.
