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Give reasons for the following observation: pKb of aniline is lower than the m-nitroaniline. - Chemistry

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प्रश्न

Give reasons for the following observation:

pKb of aniline is lower than the m-nitroaniline.

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उत्तर

pKb of aniline is lower than the m-nitro aniline.The basic strength of aniline is more than m-nitroaniline. pKb value is inversely proportional to basic strength. The presence of an Electron withdrawing group decreases basic strength.

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