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प्रश्न
Read the following reaction and answer the questions given below.
\[\begin{array}{cc}
\phantom{..............................}\ce{CH3}\\\phantom{...........................}|\\\ce{CH3 - C = CH2 + HBr ->[benzoyl][peroxide] CH3 - CH - CH2Br}\\
|\phantom{....................................}\\
\ce{CH3}\phantom{.................................}\end{array}\]
- Write the IUPAC name of the product.
- State the rule that governs the formation of this product.
उत्तर
- IUPAC name of the product: 1-Bromo-2-methylpropane
- Anti-Markownikov’s rule/Kharasch effect/peroxide effect: It states that the addition of HBr to an unsymmetrical alkene in the presence of organic peroxide (R–O–O–R) takes place in the opposite orientation to that suggested by Markovnikov's rule.
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संबंधित प्रश्न
Acetone and acetaldehyde are the ozonolysis products of an alkene. Write the structural formula of an alkene and give IUPAC name of it.
What is the action of following on but-2-ene?
dil. alkaline KMnO4
What is the action of following on but-2-ene?
acidic KMnO4
The compound that will react most readily with gaseous bromine has the formula (NEET) ______.
Peroxide effect (Kharasch effect) can be studied in case of ______.
Give IUPAC name for the following compound.
\[\ce{(CH3)3 C – C ≡ C – CH (CH3)2}\]
An alkyl halide with molecular formula C6H13Br on dehydro halogenation gave two isomeric alkenes X and Y with molecular formula C6H12. On reductive ozonolysis, X and Y gave four compounds CH3COCH3, CH3CHO, CH3CH, CHO and (CH3)2 CHCHO. Find the alkyl halide.
Complete the following:
\[\ce{2 - butyne ->[Lindlar Catalyst]}\]
Identify the CORRECT statement about the following compound.
(C2H5)2NH
\[\ce{A + HBr ->[Peroxide] 1-Bromo-2-methylheptane}\]
Identify A.
Saytzeff's rule states that ____________ product is the major product in dehydrohalogenation of an alkyl halide.
Addition of HCl to ____________ mainly gives 2-chloro-2-methylbutane.
Which of the following in Baeyer's reagent?
Which of following properties is not exhibited by benzene?
Acetone and acetaldehyde are the ozonolysis products of an alkene. Write the structural formula of an alkene and give the IUPAC name of it.
Read the following reaction and answer the questions given below.
\[\begin{array}{cc}
\ce{CH3 - C = CH2 + HBr ->[benzoyl][peroxide] CH3}\\
\phantom{.....}|\phantom{........................}|\phantom{}\\
\phantom{.................}\ce{CH3}\phantom{..............}\ce{CH3 - CH\ - CH2Br}\phantom{}\
\end{array}\]
a. Write the IUPAC name of the product.
b. State the rule that governs the formation of this product.
Acetone and acetaldehyde are the ozonolysis products of an alkene. Write the structural formula of an alkene and give the IUPAC name of it.
Write the balanced chemical reaction for preparation of ethane from Ethyl magnesium iodide.
What is the action of following on but-2-ene?
dil alkaline KMnO4
Read the following reaction and answer the questions given below.
\[\begin{array}{cc}
\phantom{...............................}\ce{CH3}\\
\phantom{............................}|\\
\ce{CH3 - C = CH2 + HBr ->[benzoyl][peroxide] CH3 - CH - CH2Br}\\
|\phantom{....................................}\\
\ce{CH3}\phantom{.................................}\\
\end{array}\]
- Write IUPAC name of the product.
- State the rule that governs formation of this product.
Acetone and acetaldehyde are the ozonolysis products of an alkene. Write the structural formula of an alkene and give IUPAC name of it.
Write the reaction to convert propene to isopropyl alcohol.
What is the action of following on but-2-ene ?
dil. alkaline \[\ce{KMnO4}\]
What is the action of following on but-2-ene?
dil. alkaline \[\ce{KMnO4}\]
What is the action of following on but-2-ene ?
dil. alkaline \[\ce{KMnO4}\]
Acetone and acetaldehyde are the ozonolysis products of an alkene. Write the structural formula of an alkene and give IUPAC name of it.
