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प्रश्न
State second law of electrolysis
State Faraday’s second law of electrolysis
उत्तर
Second law : It states that when the same amount of electricity is passed through different cells containing different electrolytes and arranged in series, the amount of substances oxidized or reduced at the representive electrode are directly proportional to their chemical equavalent masses
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संबंधित प्रश्न
State the first law of electrolysis
Consider the reaction: \[\ce{Cr2O^{2-}_7 + 14H^+ + 6e^- -> 2Cr^{3+} + 7H2O}\]
What is the quantity of electricity in coulombs needed to reduce 1 mol of \[\ce{Cr2O^{2-}_7}\]?
How much charge is required for the following reduction:
1 mol of \[\ce{Cu^{2+}}\] to \[\ce{Cu}\]?
Three electrolytic cells A, B, C containing solutions of \[\ce{ZnSO4}\], \[\ce{AgNO3}\] and \[\ce{CuSO4}\], respectively, are connected in series. A steady current of 1.5 amperes was passed through them until 1.45 g of silver deposited at the cathode of cell B. How long did the current flow? What mass of copper and zinc were deposited?
Write any two uses of H2SO4
Draw neat labelled diagram of electrolytic refining of blister copper
Explain Faraday’s second law of electrolysis
How many faradays of electricity are required to produce 13 gram of aluminium from aluminium chloride solution? (Given: Molar mass of Al = 27.0-gram mol–1)
Following reactions occur at cathode during the electrolysis of aqueous copper(II) chloride solution :
On the basis of their standard reduction electrode potential (E°) values, which reaction is feasible at the cathode and why ?
Solve the following question.
A steady current of 2 amperes was passed through two electrolytic cells X and Y connected in series containing electrolytes FeSO4 and ZnSO4 until 2.8 g of Fe deposited at the cathode of cell X. How long did the current flow? Calculate the mass of Zn deposited at the cathode of cell Y.
(Molar mass : Fe = 56 g mol–1, Zn = 65.3 g mol–1, 1F = 96500 C mol–1)
Electrolytic cell uses electrical energy to bring about ____________.
According to Faraday’s First Law of Electrolysis, the amount of chemical reaction which occurs at any electrode during electrolysis by a current is proportional to the ____________.
What will happen during the electrolysis of aqueous solution of \[\ce{CuSO4}\] by using platinum electrodes?
(i) Copper will deposit at cathode.
(ii) Copper will deposit at anode.
(iii) Oxygen will be released at anode.
(iv) Copper will dissolve at anode.
Aqueous copper sulphate solution and aqueous silver nitrate solution are electrolysed by 1 ampere current for 10 minutes in separate electrolytic cells. Will the mass of copper and silver deposited on the cathode be same or different? Explain your answer.
Assertion: Electrolysis of NaCl solution gives chlorine at anode instead of O2.
Reason: Formation of oxygen at anode requires overvoltage.
Consider the figure and answer the following question.
Cell ‘A’ has ECell = 2V and Cell ‘B’ has ECell = 1.1V which of the two cells ‘A’ or ‘B’ will act as an electrolytic cell. Which electrode reactions will occur in this cell?
Time Required to deposite one millimole of aluminium metal by the passage of 9.65 ampere through aqueous solution of aluminium is
When during electrolysis of a solution of Ag No3, 9650 coulombs of charge pass through the electroplating bath, the mass of silver deposite on the cathode will be:-
Given `1/a` = 0.5 CM–1, R = 50 ohm, N = 1.0 then equivalent conductance of electrolytic cell is
The quantity of electricity needed to separately electrolyse 1 M solution of ZnSO4, AlCl3, and AgNO3 completely is in the ratio of ______.
What is the quantity of electricity in Coulombs required to produce 4.8 g of Mg from molten MgCl2? How much Ca will be produced if the same amount of electricity was passed through molten CaCl2? (Atomic mass of Mg = 24 u, atomic mass of Ca = 40 u).
Through an aqueous solution of an unknown salt of metal M (M = 200 g/mol) a current of 1.93 A is passed for 50 min. If 4 g of metal is produced at cathode. The charge on metal ion in solution is ______.
Assertion (A): During electrolysis of aqueous copper sulphate solution using copper electrodes hydrogen gas is released at the cathode.
Reason (R): The electrode potential of Cu2+/Cu is greater than that of H+/H2.
Select the most appropriate answer from the options given below:
