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प्रश्न
State the first law of electrolysis
उत्तर १
First law : It states that the amount of substance that undergoes oxidation or reduction at each electrode during electrolysis is directly proportional to the amount of electricity that passes through the cell.
उत्तर २
It is one of the primary laws of electrolysis. It states, during electrolysis, the amount of chemical reaction which occurs at any electrode under the influence of electrical energy is proportional to the quantity of electricity passed through the electrolyte.
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संबंधित प्रश्न
On calculating the strength of current in amperes if a charge of 840C (coulomb) passes through an electrolyte in 7 minutes, it will be
- 1
- 2
- 3
- 4
The charge of how many coulomb is required to deposit 1.0 g of sodium metal (molar mass 23.0 g mol-1) from sodium ions is -
- 2098
- 96500
- 193000
- 4196
Write any four applications of electrochemical series
Using the E° values of A and B, predict which is better for coating the surface of iron [E°(Fe+2/Fe) = -0.44V] to prevent corrosion and why?
Given: E° (A+2/A)=-2.37 V: E°(B+2/B)= -0.14V
Following reactions occur at cathode during the electrolysis of aqueous sodium chloride solution:
Na+(aq) + e− ⟶ Na (s) E0 = 2.71 V
H+(aq) + e− ⟶ `1/2` H2 (g) E0 = 0.00 V
On the basis of their standard reduction electrode potential (E0) values, which reaction is feasible at the cathode and why?
Suggest a list of metals that are extracted electrolytically.
A solution of \[\ce{Ni(NO3)2}\] is electrolysed between platinum electrodes using a current of 5 amperes for 20 minutes. What mass of \[\ce{Ni}\] is deposited at the cathode?
Three electrolytic cells A, B, C containing solutions of \[\ce{ZnSO4}\], \[\ce{AgNO3}\] and \[\ce{CuSO4}\], respectively, are connected in series. A steady current of 1.5 amperes was passed through them until 1.45 g of silver deposited at the cathode of cell B. How long did the current flow? What mass of copper and zinc were deposited?
On passing 1.5 F charge, the number of moles of aluminium deposited at cathode are _______ [Molar mass of Al = 27 gram mol–1]
(A) 1.0
(B) 13.5
(C) 0.50
(D) 0.75
Draw neat labelled diagram of electrolytic refining of blister copper
What is the ratio of volumes of H2 and O2 liberated during electrolysis of acidified water?
(A) 1 : 2
(B) 2 : 1
(C) 1 : 8
(D) 8 : 1
State second law of electrolysis
Explain Faraday’s second law of electrolysis
Calculate the mass of Ag deposited at cathode when a current of 2 amperes was passed through a solution of AgNO3 for 15 minutes.
(Given : Molar mass of Ag = 108 g mol−1 lF = 96500 C mol−1)
How many faradays of electricity are required to produce 13 gram of aluminium from aluminium chloride solution? (Given: Molar mass of Al = 27.0-gram mol–1)
Following reactions occur at cathode during the electrolysis of aqueous copper(II) chloride solution :
On the basis of their standard reduction electrode potential (E°) values, which reaction is feasible at the cathode and why ?
Electrolytic cell uses electrical energy to bring about ____________.
According to Faraday’s First Law of Electrolysis, the amount of chemical reaction which occurs at any electrode during electrolysis by a current is proportional to the ____________.
What will happen during the electrolysis of aqueous solution of CuSO4 in the presence of Cu electrodes?
(i) Copper will deposit at cathode.
(ii) Copper will dissolve at anode.
(iii) Oxygen will be released at anode.
(iv) Copper will deposit at anode.
Aqueous copper sulphate solution and aqueous silver nitrate solution are electrolysed by 1 ampere current for 10 minutes in separate electrolytic cells. Will the mass of copper and silver deposited on the cathode be same or different? Explain your answer.
Assertion: Electrolysis of NaCl solution gives chlorine at anode instead of O2.
Reason: Formation of oxygen at anode requires overvoltage.
Consider the figure and answer the following question.
Cell ‘A’ has ECell = 2V and Cell ‘B’ has ECell = 1.1V which of the two cells ‘A’ or ‘B’ will act as an electrolytic cell. Which electrode reactions will occur in this cell?
Given `1/a` = 0.5 CM–1, R = 50 ohm, N = 1.0 then equivalent conductance of electrolytic cell is
On Electrolysis of dilute sulphuric acid using platinum electrodes, the product obtained at the anode will be.
What is the quantity of electricity in Coulombs required to produce 4.8 g of Mg from molten MgCl2? How much Ca will be produced if the same amount of electricity was passed through molten CaCl2? (Atomic mass of Mg = 24 u, atomic mass of Ca = 40 u).
Assertion (A): During electrolysis of aqueous copper sulphate solution using copper electrodes hydrogen gas is released at the cathode.
Reason (R): The electrode potential of Cu2+/Cu is greater than that of H+/H2.
Select the most appropriate answer from the options given below:
How much electricity in terms of Faraday is required to produce 40.0 g of \[\ce{Al}\] from molten \[\ce{Al2O3}\]?
(Given: Molar mass of Aluminium is 27 g mol−1.)
