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प्रश्न
Which of the following statements concerning the quantum numbers are correct?
(i) Angular quantum number determines the three dimensional shape of the orbital.
(ii) The principal quantum number determines the orientation and energy of the orbital.
(iii) Magnetic quantum number determines the size of the orbital.
(iv) Spin quantum number of an electron determines the orientation of the spin of electron relative to the chosen axis.
उत्तर
(i) Angular quantum number determines the three dimensional shape of the orbital.
(iv) Spin quantum number of an electron determines the orientation of the spin of electron relative to the chosen axis.
Explanation:
(i) Azimuthal quantum number l is also known as orbital angular momentum or subsidiary quantum number. It determines three-dimensional shape of the orbital.
(ii) The principal quantum number determines the size of the orbit.
(iii) Magnetic quantum number determines the orientation of the electron cloud in a subshell.
(iv) An electron spins around its own’ axis, much in a similar way as earth spins around its own axis while revolving around the sun. In other words, an electron has, besides charge and mass, intrinsic spin angular quantum number.
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संबंधित प्रश्न
Explain in brief, the significance of the azimuthal quantum number.
Using the concept of quantum numbers, calculate the maximum numbers of electrons present in the ‘M’ shell. Give their distribution in shells, subshells, and orbitals.
Indicate the number of unpaired electron in:
Cr (Z = 24)
Which of the following properties of atom could be explained correctly by Thomson Model of atom?
Which of the following sets of quantum numbers are correct?
| `n` | `l` | `m_l` | |
| (i) | 1 | 1 | +2 |
| (ii) | 2 | 1 | +1 |
| (iii) | 3 | 2 | –2 |
| (iv) | 3 | 4 | –2 |
Which of the following orbitals are degenerate?
3dxy, 4dxy 3dz2, 3dyz, 4dyz, 4dz2
The arrangement of orbitals on the basis of energy is based upon their (n + l) value. Lower the value of (n + l), lower is the energy. For orbitals having same values of (n + l), the orbital with lower value of n will have lower energy.
Based upon the above information, solve the questions given below:
Which of the following orbitals has the lowest energy?
4d, 4f, 5s, 5p
The electronic configuration of valence shell of Cu is 3d104s1 and not 3d94s2. How is this configuration explained?
Match species given in Column I with the electronic configuration given in Column II.
| Column I | Column II |
| (i) \[\ce{Cr}\] | (a) [Ar]3d84s0 |
| (ii) \[\ce{Fe^{2+}}\] | (b) [Ar]3d104s1 |
| (iii) \[\ce{Ni^{2+}}\] | (c) [Ar]3d64s0 |
| (iv) \[\ce{Cu}\] | (d) [Ar] 3d54s1 |
| (e) [Ar]3d64s2 |
Which of the following is not the permissible arrangement of electrons in an atom?
